Superoxide Ions Entrapped in Water Cages of Ionic Clathrate Hydrates

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In the present work, we first described the stable entrapment of the Superoxide ions in gamma-irradiated (Me(4)NOH + O(2)) clathrate hydrate. Owing to peculiar direct guest-guest ionic interaction, the lattice structure of gamma-irradiated (Me(4)NOH + O(2)) clathrate hydrate shows significant change of lattice contraction behavior even at relatively high temperature (120 K). Such Findings are expected to provide useful information for a better understanding of unrevealed nature (such as icy nanoreactor concept, ice-based functional material synthesis and lattice tuning by specific ionic guests) of clathrate hydrate fields.
Publisher
AMER CHEMICAL SOC
Issue Date
2010-03
Language
English
Article Type
Article
Keywords

GUEST MOLECULES; ESR; TRANSITION; INCLUSION; ELECTRON; TIO2

Citation

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.132, no.11, pp.3694 - +

ISSN
0002-7863
DOI
10.1021/ja1004762
URI
http://hdl.handle.net/10203/94607
Appears in Collection
CBE-Journal Papers(저널논문)
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