Synthesis of L-Cladinose Using Enantioselective Desymmetrization

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L-Cladinose, a neutral sugar found in erythromycins and azithromycins, has been synthesized efficiently using enantioselective monobenzoylation of 2-propenylglycerol in the presence of the imine-CuCl(2) catalysts to elaborate the stereogenic quaternary center.
Publisher
GEORG THIEME VERLAG KG
Issue Date
2008-10
Language
English
Article Type
Article
Keywords

ASYMMETRIC TOTAL SYNTHESIS; ETUDE DES PRODUITS; MACROLIDE ANTIBIOTICS; KEDARCIDIN CHROMOPHORE; L-MYCAROSE; ERYTHROMYCIN; SPIRAMYCINE; DEGRADATION; LEUCOMYCIN; CARACTERISATION

Citation

SYNLETT, no.16, pp.2526 - 2528

ISSN
0936-5214
DOI
10.1055/s-2008-1078046
URI
http://hdl.handle.net/10203/91003
Appears in Collection
CH-Journal Papers(저널논문)
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