Catalytic enantioselective Mukaiyama-Michael reaction of 2-(trimethylsilyloxy)furan with alpha '-phenylsulfonyl enones

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dc.contributor.authorYang, Hyeyeonko
dc.contributor.authorKim, Sung Gakko
dc.date.accessioned2013-03-07T06:20:03Z-
dc.date.available2013-03-07T06:20:03Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2008-03-
dc.identifier.citationSYNLETT, no.4, pp.555 - 560-
dc.identifier.issn0936-5214-
dc.identifier.urihttp://hdl.handle.net/10203/89589-
dc.description.abstractThe Mukaiyama-Michael reaction of 2-(trimethylsilyloxy)furan with alpha'-phenylsulfonyl enones using bis(oxazoline)copper(II) complexes as chiral catalyst provides the gamma-butenolides in high enantio- and diastereoselectivity. This approach is very useful for the enantioselective synthesis of gamma-butenolide derivatives under chiral Lewis acid catalysis.-
dc.languageEnglish-
dc.publisherGeorg Thieme Verlag Kg-
dc.subjectDIELS-ALDER REACTIONS-
dc.subjectCHIRAL LEWIS-ACIDS-
dc.subjectC(2)-SYMMETRIC COPPER(II) COMPLEXES-
dc.subject4-SUBSTITUTED GAMMA-LACTONES-
dc.subjectSILYL ENOL ETHERS-
dc.subjectVINYL ETHERS-
dc.subjectALPHA,BETA-UNSATURATED KETONES-
dc.subjectSILYLKETENE ACETALS-
dc.subjectADDITION-REACTION-
dc.subjectALDOL ADDITIONS-
dc.titleCatalytic enantioselective Mukaiyama-Michael reaction of 2-(trimethylsilyloxy)furan with alpha '-phenylsulfonyl enones-
dc.typeArticle-
dc.identifier.wosid000254242500016-
dc.identifier.scopusid2-s2.0-40949136596-
dc.type.rimsART-
dc.citation.issue4-
dc.citation.beginningpage555-
dc.citation.endingpage560-
dc.citation.publicationnameSYNLETT-
dc.identifier.doi10.1055/s-2008-1032074-
dc.contributor.localauthorKim, Sung Gak-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorasymmetric catalysis-
dc.subject.keywordAuthorMichael additions-
dc.subject.keywordAuthorLewis acids-
dc.subject.keywordAuthorligands-
dc.subject.keywordAuthorlactones-
dc.subject.keywordPlusDIELS-ALDER REACTIONS-
dc.subject.keywordPlusCHIRAL LEWIS-ACIDS-
dc.subject.keywordPlusC(2)-SYMMETRIC COPPER(II) COMPLEXES-
dc.subject.keywordPlus4-SUBSTITUTED GAMMA-LACTONES-
dc.subject.keywordPlusSILYL ENOL ETHERS-
dc.subject.keywordPlusVINYL ETHERS-
dc.subject.keywordPlusALPHA,BETA-UNSATURATED KETONES-
dc.subject.keywordPlusSILYLKETENE ACETALS-
dc.subject.keywordPlusADDITION-REACTION-
dc.subject.keywordPlusALDOL ADDITIONS-
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