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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Enantioselective radical conjugate addition to alpha '-phosphoric enones

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dc.contributor.authorLee, Sunggiko
dc.contributor.authorKim, Sung Gakko
dc.date.accessioned2013-03-06T14:47:28Z-
dc.date.available2013-03-06T14:47:28Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2008-10-
dc.identifier.citationORGANIC LETTERS, v.10, no.19, pp.4255 - 4258-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10203/87301-
dc.description.abstractCatalytic enantioselective radical conjugate addition reactions using alpha'-phosphoric enone templates have been studied. The C(2)-symmetric bisoxazoline-zinc(II) complex proves to be effective for high enantioselectivities and chemical yields. In addition, intermediate alpha-carbonyl alkyl radicals could be trapped with allyltributylstannane to afford anti-isomers as major products with high enantioselectivities.-
dc.languageEnglish-
dc.publisherAmer Chemical Soc-
dc.subjectLEWIS-ACIDS-
dc.subjectDIELS-ALDER-
dc.subjectCATALYSIS-
dc.subjectBIS(OXAZOLINE)-
dc.subjectCOMPLEXES-
dc.subjectFRIEDEL-
dc.titleEnantioselective radical conjugate addition to alpha '-phosphoric enones-
dc.typeArticle-
dc.identifier.wosid000259557700026-
dc.identifier.scopusid2-s2.0-61349109998-
dc.type.rimsART-
dc.citation.volume10-
dc.citation.issue19-
dc.citation.beginningpage4255-
dc.citation.endingpage4258-
dc.citation.publicationnameORGANIC LETTERS-
dc.identifier.doi10.1021/ol8017177-
dc.embargo.liftdate9999-12-31-
dc.embargo.terms9999-12-31-
dc.contributor.localauthorKim, Sung Gak-
dc.type.journalArticleArticle-
dc.subject.keywordPlusLEWIS-ACIDS-
dc.subject.keywordPlusDIELS-ALDER-
dc.subject.keywordPlusCATALYSIS-
dc.subject.keywordPlusBIS(OXAZOLINE)-
dc.subject.keywordPlusCOMPLEXES-
dc.subject.keywordPlusFRIEDEL-
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