Catalytic enantioselective Friedel-Crafts alkylations of indoles with alpha '-phosphoric enones

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The C-2-symmetric bis(oxazoline) copper(II) complex proves to be an excellent catalyst in the Friedel-Crafts alkylation of indoles with alpha '-phosphoric enones. The enantioselectivities of this reaction are obtained in up to 98% ee.
Publisher
Amer Chemical Soc
Issue Date
2007-06
Language
English
Article Type
Article
Keywords

BIS(OXAZOLINYL)PYRIDINE-SCANDIUM(III) TRIFLATE COMPLEXES; BETA-KETO PHOSPHONATES; C-H BONDS; THEORETICAL INVESTIGATIONS; HETEROAROMATIC-COMPOUNDS; ASYMMETRIC EPOXIDATION; COPPER(II) COMPLEXES; FORMAL SYNTHESIS; DEPHOSPHONYLATION; ALKALOIDS

Citation

ORGANIC LETTERS, v.9, no.12, pp.2281 - 2284

ISSN
1523-7060
DOI
10.1021/ol070548b
URI
http://hdl.handle.net/10203/86340
Appears in Collection
CH-Journal Papers(저널논문)
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