The 530 nm system of KRb observed in a pulsed molecular beam: New electric quadrupole transitions (1 (1)Delta-X (1)Sigma(+))

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dc.contributor.authorLee, Yko
dc.contributor.authorYun, Cko
dc.contributor.authorYoon, Yko
dc.contributor.authorKim, Tko
dc.contributor.authorKim, Bongsooko
dc.date.accessioned2013-03-04T17:40:28Z-
dc.date.available2013-03-04T17:40:28Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2001-10-
dc.identifier.citationJOURNAL OF CHEMICAL PHYSICS, v.115, no.16, pp.7413 - 7419-
dc.identifier.issn0021-9606-
dc.identifier.urihttp://hdl.handle.net/10203/83489-
dc.description.abstractNew electronic transitions of KRb are identified near 530 nm by resonance enhanced two photon ionization study in a supersonic molecular beam. The rotational structure shows O, P, Q, R, and S branches. From the high resolution rotational analysis and comparison with the spectra of other alkali diatomic molecules we assign the observed bands to the 1 (1)Delta -X (1)Sigma (+) transitions of KRb, which are allowed by electric quadrupole radiation. We obtain molecular constants for the upper electronic state of (KRb)-K-39-Rb-85 as omega (e)=64.624 1(35)cm(-1), T-e=18 991.011 0(14)cm(-1), B-e(')=0.035 703 9(10)cm(-1), and R-e=4.204 55(6) A. Another new electronic transition observed in the same wavelength region is assigned to the 3 (3)Sigma (+)-X (1)Sigma (+) transition from the comparison with ab initio calculations. (C) 2001 American Institute of Physics.-
dc.languageEnglish-
dc.publisherAMER INST PHYSICS-
dc.subjectRESONANCE POLARIZATION SPECTROSCOPY-
dc.subject2-PHOTON IONIZATION SPECTROSCOPY-
dc.subjectDIATOMIC-MOLECULES-
dc.subjectSTATE-
dc.subjectBANDS-
dc.subjectCS2-
dc.subject(KRB)-K-39-RB-85-
dc.subjectPREDISSOCIATION-
dc.subjectRBCS-
dc.subjectK-2-
dc.titleThe 530 nm system of KRb observed in a pulsed molecular beam: New electric quadrupole transitions (1 (1)Delta-X (1)Sigma(+))-
dc.typeArticle-
dc.identifier.wosid000171719200010-
dc.identifier.scopusid2-s2.0-0035935351-
dc.type.rimsART-
dc.citation.volume115-
dc.citation.issue16-
dc.citation.beginningpage7413-
dc.citation.endingpage7419-
dc.citation.publicationnameJOURNAL OF CHEMICAL PHYSICS-
dc.contributor.localauthorKim, Bongsoo-
dc.contributor.nonIdAuthorLee, Y-
dc.contributor.nonIdAuthorYun, C-
dc.contributor.nonIdAuthorYoon, Y-
dc.contributor.nonIdAuthorKim, T-
dc.type.journalArticleArticle-
dc.subject.keywordPlusRESONANCE POLARIZATION SPECTROSCOPY-
dc.subject.keywordPlus2-PHOTON IONIZATION SPECTROSCOPY-
dc.subject.keywordPlusDIATOMIC-MOLECULES-
dc.subject.keywordPlusSTATE-
dc.subject.keywordPlusBANDS-
dc.subject.keywordPlusCS2-
dc.subject.keywordPlus(KRB)-K-39-RB-85-
dc.subject.keywordPlusPREDISSOCIATION-
dc.subject.keywordPlusRBCS-
dc.subject.keywordPlusK-2-
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