In-mediated allylation of alpha-keto esters with allyl halides

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The chemoselective reaction of alpha -keto esters with allyl halides, propargyl bromides, and allenyl bromide using indium metal afforded alpha -hydroxy-gamma,delta -unsaturated esters in good to excellent yields under mild conditions.
Publisher
MARCEL DEKKER INC
Issue Date
2001
Language
English
Article Type
Article
Keywords

AQUEOUS-MEDIA; ORGANOMETALLIC REACTIONS; CARBONYL ALLYLATION; INDIUM; ALDEHYDES; SELECTIVITY; ACID

Citation

SYNTHETIC COMMUNICATIONS, v.31, no.20, pp.3189 - 3196

ISSN
0039-7911
URI
http://hdl.handle.net/10203/81364
Appears in Collection
CH-Journal Papers(저널논문)
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