Synthesis, characterization, and ion conductivities of the plasticized polymer electrolytes based on the terpolymer ionomer

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The polymer electrolytes composed of poly(acrylonitrile-co-methyl methacrylate-co-lithium methacrylate) [P(AN-co-MMA-co-LiMA)], ethylene carbonate (EC), LiClO4 salts, and silica have been prepared. The introduction of the MMA unit into the P(AN-co-LiMA) matrix made the polymer matrix soluble in a rather volatile solvent such as tetrahydrofuran (THF), which is expected to enhance the process for preparing the polymer electrolyte, The ion groups in the P(AN-co-MMA-coLiMA) were found to prevent EC from crystalling through their ion-dipole interactions with the polar groups in the EC. This suppression of the EC crystallization could lead to the enhancement of the ion conductivity at subambient temperature. Copyright (C) 2000 John Wiley & Sons, Ltd.
Publisher
JOHN WILEY & SONS LTD
Issue Date
2000-08
Language
English
Article Type
Article
Keywords

LITHIUM BATTERIES; GEL ELECTROLYTES; HYBRID FILMS; POLYACRYLONITRILE; BLEND

Citation

POLYMERS FOR ADVANCED TECHNOLOGIES, v.11, no.8-12, pp.518 - 523

ISSN
1042-7147
URI
http://hdl.handle.net/10203/74129
Appears in Collection
CBE-Journal Papers(저널논문)
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