DC Field | Value | Language |
---|---|---|
dc.contributor.author | Chang, Sukbok | ko |
dc.contributor.author | Jones, L | ko |
dc.contributor.author | Wang, CM | ko |
dc.contributor.author | Henling, LM | ko |
dc.contributor.author | Grubbs, RH | ko |
dc.date.accessioned | 2013-02-28T06:38:21Z | - |
dc.date.available | 2013-02-28T06:38:21Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 1998-08 | - |
dc.identifier.citation | ORGANOMETALLICS, v.17, no.16, pp.3460 - 3465 | - |
dc.identifier.issn | 0276-7333 | - |
dc.identifier.uri | http://hdl.handle.net/10203/73292 | - |
dc.description.abstract | A novel series of Schiff-base-substituted ruthenium carbene complexes have been prepared by the treatment of RuCl2(=CHPh)(PCy3)(2) with a variety of Schiff-base ligands as the thallium salts. Modification of the Schiff-base electronic and/or structural substituents allowed for the tuning of the complexes activities in olefin metathesis reactions. The structures of the complexes were unambiguously characterized by NMR studies and X-ray analysis. These newly prepared complexes are highly stable to air, moisture, and temperature and even exhibit catalytic activity in polar protic solvents. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | RING-CLOSING METATHESIS | - |
dc.subject | CARBENE COMPLEX | - |
dc.subject | ACYCLIC OLEFINS | - |
dc.subject | AMINO-ACIDS | - |
dc.subject | POLYMERIZATION | - |
dc.subject | RUCL2(=CHR&apos | - |
dc.subject | )(PR(3))(2) | - |
dc.subject | MEDIA | - |
dc.subject | ROMP | - |
dc.title | Synthesis and characterization of new ruthenium-based olefin metathesis catalysts coordinated with bidentate Schiff-base ligands | - |
dc.type | Article | - |
dc.identifier.wosid | 000075378500013 | - |
dc.identifier.scopusid | 2-s2.0-0001645448 | - |
dc.type.rims | ART | - |
dc.citation.volume | 17 | - |
dc.citation.issue | 16 | - |
dc.citation.beginningpage | 3460 | - |
dc.citation.endingpage | 3465 | - |
dc.citation.publicationname | ORGANOMETALLICS | - |
dc.identifier.doi | 10.1021/om970910y | - |
dc.contributor.localauthor | Chang, Sukbok | - |
dc.contributor.nonIdAuthor | Jones, L | - |
dc.contributor.nonIdAuthor | Wang, CM | - |
dc.contributor.nonIdAuthor | Henling, LM | - |
dc.contributor.nonIdAuthor | Grubbs, RH | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | RING-CLOSING METATHESIS | - |
dc.subject.keywordPlus | CARBENE COMPLEX | - |
dc.subject.keywordPlus | ACYCLIC OLEFINS | - |
dc.subject.keywordPlus | AMINO-ACIDS | - |
dc.subject.keywordPlus | POLYMERIZATION | - |
dc.subject.keywordPlus | RUCL2(=CHR&apos | - |
dc.subject.keywordPlus | )(PR(3))(2) | - |
dc.subject.keywordPlus | MEDIA | - |
dc.subject.keywordPlus | ROMP | - |
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