Synthesis of ketones with alkyl phosphonates and nitriles as acyl cation equivalent: Application of dephosphonylation reaction of beta-functionalized phosphonate with hydride

The preparation of several alpha-substituted ketones is performed in a one-pot procedure with alkyl phosphonates and aromatic nitriles by subsequent treatment of LiAlH4. A new method for nitriles used as an acyl cation equivalent is described.
Publisher
Taylor & Francis Inc
Issue Date
1997
Language
ENG
Keywords

ONE-POT SYNTHESIS

Citation

SYNTHETIC COMMUNICATIONS, v.27, no.19, pp.3333 - 3339

ISSN
0039-7911
URI
http://hdl.handle.net/10203/73238
Appears in Collection
RIMS Journal Papers
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