Facile Nucleophilic Substitution of 3-tert-Butyldimethylsilyloxyalk-2-enyl-phosphonium Salts

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dc.contributor.authorKim, Sung Gakko
dc.date.accessioned2013-02-28T00:09:17Z-
dc.date.available2013-02-28T00:09:17Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued1999-09-
dc.identifier.citationTETRAHEDRON LETTERS, v.40, no.38, pp.6975 - 6978-
dc.identifier.issn0040-4039-
dc.identifier.urihttp://hdl.handle.net/10203/71643-
dc.description.abstractPhosphoniosilylation of alpha,beta-enones with TBSOTf and triphenylphosphine at 0 degrees C affords 3-tert-butyldimethylsilyloxyalk-2-enylphosphonium salts, which undergo facile nucleophilic substitution with various nucleophiles to give 3-substituted silyl enol ethers in good yields. (C) 1999 Elsevier Science Ltd. All rights reserved.-
dc.languageEnglish-
dc.publisherPergamon-Elsevier Science Ltd-
dc.subjectCONJUGATE ADDITION-
dc.subjectENONES-
dc.subjectPHOSPHONIOSILYLATION-
dc.titleFacile Nucleophilic Substitution of 3-tert-Butyldimethylsilyloxyalk-2-enyl-phosphonium Salts-
dc.typeArticle-
dc.identifier.wosid000082402600025-
dc.identifier.scopusid2-s2.0-0033578639-
dc.type.rimsART-
dc.citation.volume40-
dc.citation.issue38-
dc.citation.beginningpage6975-
dc.citation.endingpage6978-
dc.citation.publicationnameTETRAHEDRON LETTERS-
dc.contributor.localauthorKim, Sung Gak-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorphosphoniosilylation-
dc.subject.keywordAuthornucleophilic substitution-
dc.subject.keywordAuthor3-substituted silyl enol ether-
dc.subject.keywordPlusCONJUGATE ADDITION-
dc.subject.keywordPlusENONES-
dc.subject.keywordPlusPHOSPHONIOSILYLATION-
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