DETERMINATION OF ADIABATIC IONIZATION-POTENTIALS OF CS2 AND CS3 IN A VERY COLD MOLECULAR-BEAM USING TIME-OF-FLIGHT MASS-SPECTROMETRY

The adiabatic ionization potentials Of Cs2 and Cs3 are measured in a pulsed supersonic jet using one-photon ionization and time-of-flight mass spectrometry. The ionization energies are determined to be IP(CS2) = 29205.5 +/- 1.0 cm-1 and IP(Cs3) = 24690 +/- 30 cm-1. The dissociation energy of the Cs2+ ion is determined as D(e)(Cs2+) = 5845.7 +/- 2.0 cm-1.The determined ionization energy Of CS2 and the dissociation energy of Cs2+ ion show good agreement with theoretical predictions.
Publisher
ELSEVIER SCIENCE BV
Issue Date
1993-01
Language
ENG
Keywords

GROUND-STATE PROPERTIES; DIMERS; CS-2

Citation

CHEMICAL PHYSICS LETTERS, v.202, no.5, pp.437 - 441

ISSN
0009-2614
DOI
10.1016/0009-2614(93)90067-B
URI
http://hdl.handle.net/10203/65867
Appears in Collection
CH-Journal Papers(저널논문)
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