DC Field | Value | Language |
---|---|---|
dc.contributor.author | Park, Joon Taik | ko |
dc.contributor.author | WOO, BW | ko |
dc.contributor.author | CHUNG, JH | ko |
dc.contributor.author | SHIM, SC | ko |
dc.contributor.author | LEE, JH | ko |
dc.contributor.author | LIM, SS | ko |
dc.contributor.author | SUH, IH | ko |
dc.date.accessioned | 2013-02-25T22:55:26Z | - |
dc.date.available | 2013-02-25T22:55:26Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 1994-09 | - |
dc.identifier.citation | ORGANOMETALLICS, v.13, no.9, pp.3384 - 3386 | - |
dc.identifier.issn | 0276-7333 | - |
dc.identifier.uri | http://hdl.handle.net/10203/65863 | - |
dc.description.abstract | The reaction, of Os-3(CO)(9)(C(2)R(2)) (R = Tol, Ph; Tol = p-C(6)H(4)Me) with Cp(CO)(2)W=CTol (Cp = eta(5)-C5H5) produces an alkylidyne-alkyne complex CpWOs(3)(CO)(10)(mu(3)-eta(2)-C(2)R(2))(mu(3)-CTol) [1a (R = Tol), 1b (R = Ph)], which is converted to two isomeric allyl complexes CpWOs(3)(CO)(10)(mu(3)-C(3)R(2)Tol) (2a,b and 3a,b) upon thermolysis. Complexes 3a,b, in which the allyl ligand is pi-coordinated to the tungsten atom, undergo consecutive allyl C-C bond cleavage to afford trialkylidyne complexes CpWOs(3)(CO)(9)(mu(3)-CR)(2)(mu 3-CTol) (5a,b) via alkylidyne-alkyne complex CpWOs(3)(CO)(10)(mu(3)-eta(2)-C(2)R(2))(mu(3)-CTol) or CpWOs(3)(Co)(10)(mu 3-eta(2)-C(2)RTol)(mu(3)-CR) (4a,b), together with formation of CpWOs(3)(CO)(8)(mu(3)-perpendicular to-C(2)R(2))(mu(3)-CTol) or CpWOs(3)(CO)(8)(mu(3)-eta(2)-perpendicular to-C(2)RTol)(mu(3)-CR) (6a,b) as a minor product. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | TRANSITION-METAL CLUSTERS | - |
dc.subject | OSMIUM CARBONYL HYDRIDES | - |
dc.subject | CRYSTAL-STRUCTURES | - |
dc.subject | TRIOSMIUM FRAMEWORK | - |
dc.subject | COMPLEXES | - |
dc.subject | ALKYNES | - |
dc.subject | PH | - |
dc.title | CONSECUTIVE C-C BOND SCISSION OF AN ALLYL LIGAND ON A WOS3 CLUSTER FRAMEWORK | - |
dc.type | Article | - |
dc.identifier.wosid | A1994PF96700004 | - |
dc.identifier.scopusid | 2-s2.0-0001603147 | - |
dc.type.rims | ART | - |
dc.citation.volume | 13 | - |
dc.citation.issue | 9 | - |
dc.citation.beginningpage | 3384 | - |
dc.citation.endingpage | 3386 | - |
dc.citation.publicationname | ORGANOMETALLICS | - |
dc.contributor.localauthor | Park, Joon Taik | - |
dc.contributor.nonIdAuthor | WOO, BW | - |
dc.contributor.nonIdAuthor | CHUNG, JH | - |
dc.contributor.nonIdAuthor | SHIM, SC | - |
dc.contributor.nonIdAuthor | LEE, JH | - |
dc.contributor.nonIdAuthor | LIM, SS | - |
dc.contributor.nonIdAuthor | SUH, IH | - |
dc.type.journalArticle | Note | - |
dc.subject.keywordPlus | TRANSITION-METAL CLUSTERS | - |
dc.subject.keywordPlus | OSMIUM CARBONYL HYDRIDES | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURES | - |
dc.subject.keywordPlus | TRIOSMIUM FRAMEWORK | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | ALKYNES | - |
dc.subject.keywordPlus | PH | - |
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