SYNTHESIS AND CRYSTAL-STRUCTURE OF [(IRCP-ASTERISK)2(MU-OH)3]2(CR2O7)CENTER-DOT-8H2O (CP-ASTERISK=ETA-5-C5ME5) - A NOVEL 2-DIMENSIONAL HYDROGEN-BONDING NETWORK

The title complex, prepared from a reaction of [(IrCp*Cl)2(mu-Cl)2] with K2CrO4 in water. has been characterized via a single-crystal X-ray diffraction study. In the solid state the tri-mu-hydroxo-diiridium complex cations. the dichromates having the staggered conformation, and the water molecules of crystallization are entirely connected by hydrogen bonds forming a novel two-dimensional layer structure.
Publisher
CHEMICAL SOC JAPAN
Issue Date
1994-07
Language
ENG
Keywords

PENTAMETHYLCYCLOPENTADIENYL-RHODIUM; DICHROMATE; ANIONS

Citation

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, v.67, no.7, pp.1968 - 1971

ISSN
0009-2673
DOI
10.1246/bcsj.67.1968
URI
http://hdl.handle.net/10203/65317
Appears in Collection
CH-Journal Papers(저널논문)
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