Effects of domain size on physical properties of a thermotropic liquid crystalline polyester

Abstract

To see the effect of domain site on the physical properties of thermotropic liquid crystalline polyester, poly[(phenylsulfonyl)-p-phenylene 1,8-octamethylene bis(4-benzoate)](NP8) having low isotropization temperature at 178℃, was synthesized via solution polymerization. Previous thermal histories were erased by treating at isotropic temperature at 200℃ and the LC domain size was controlled by annealing at liquid crystal state temperature, at 170℃. LC domains grew with annealing time and the domain growth rate was scaled as d-t0.19 at 170℃. The effect of the LC domain size on the crystallization rate was investigated. Crystallization temperature of 110℃ was chosen since the growth rate showed maximum at that temperature. Three crystal melting peaks were observed in the crystallized sample. Avrami treatment and WAXD analysis for the three different crystal structures revealed that the high temperature melting crystal has higher degree of orientation than the low temperature melting crystal. It was found that the NP8 with large domain size had the faster crystallization rate and higher isotropization temperature. The effect of domain size on the transient rheological properties showed that the larger domain size had smaller stress overshoot and N1 overshoot for the transient shear flow. The effect of domain size on the steady state rheological properties showed that the larger domain size had smaller steady state N1 values at low shear rate region.