DC Field | Value | Language |
---|---|---|
dc.contributor.advisor | Jung, Kyung-Hoon | - |
dc.contributor.advisor | 정경훈 | - |
dc.contributor.author | Yi, Hun-Jung | - |
dc.contributor.author | 이헌정 | - |
dc.date.accessioned | 2011-12-13T04:58:59Z | - |
dc.date.available | 2011-12-13T04:58:59Z | - |
dc.date.issued | 1991 | - |
dc.identifier.uri | http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=67637&flag=dissertation | - |
dc.identifier.uri | http://hdl.handle.net/10203/32607 | - |
dc.description | 학위논문(석사) - 한국과학기술원 : 화학과, 1991.2, [ iv, 39 p. ] | - |
dc.description.abstract | A vacuum ultraviolet photolysis of methyl bromide at 121.6nm(253.1kal/mol) by using the hydrogen resonance lamp was studied over the pressure range of 1-50 Torr at room temperature. The result demonstrate the two decomposition mode, i.e., the molecular elimination of HBr to frommethylene, and the C-Br bond cleavage to form methyl radical. The major products of the reaction were found to be $CH_4$, $C_2H_4$, and $C_2H_6$. The branching ratios between the molecular elimination and the methyl radical formation were 0.05:0.95. The scavenger effect was studued by adding HBr as a radical capture to obtain information about primary process. The pressure was also observed by adding inert gases, i.e., $N_2$ and He. | eng |
dc.language | eng | - |
dc.publisher | 한국과학기술원 | - |
dc.title | Recombination of methyl radical at 121.6nm | - |
dc.title.alternative | 121.6nm 에서 메틸 라디칼의 recombination에 관한 연구 | - |
dc.type | Thesis(Master) | - |
dc.identifier.CNRN | 67637/325007 | - |
dc.description.department | 한국과학기술원 : 화학과, | - |
dc.identifier.uid | 000891409 | - |
dc.contributor.localauthor | Jung, Kyung-Hoon | - |
dc.contributor.localauthor | 정경훈 | - |
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