Studies on the chemoselectivity of carbonyl groups = 카르보닐 화합물의 화학반응 선택성에 관한 연구

The chemoselectivity of carbonyl compounds have been stduied. Dimethyl sulfide and trimethylsilyl triflate(TMSOTf) selectively reacted with aldehydes to form $\alpha$-silyloxysulfonium salts in the presence of ketones at low temperature. Therefore ketone groups could chemoselectively react with other uncleophiles in the presence of aldehyde groups. The difference in the reactivity between cyclic acetals or ketals and acyclic acetals or ketals was studied for various nucleophiles.
Advisors
Kim, Sung-Gakresearcher김성각researcher
Publisher
한국과학기술원
Issue Date
1991
Identifier
67613/325007 / 000891046
Language
eng
Description

학위논문(석사) - 한국과학기술원 : 화학과, 1991.2, [ v, 60 p. ]

URI
http://hdl.handle.net/10203/32585
Link
http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=67613&flag=t
Appears in Collection
CH-Theses_Master(석사논문)
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