DC Field | Value | Language |
---|---|---|
dc.contributor.advisor | Oh, Dong-Young | - |
dc.contributor.advisor | 오동영 | - |
dc.contributor.author | Koh, Young-Joo | - |
dc.contributor.author | 고영주 | - |
dc.date.accessioned | 2011-12-13T04:58:39Z | - |
dc.date.available | 2011-12-13T04:58:39Z | - |
dc.date.issued | 1991 | - |
dc.identifier.uri | http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=67612&flag=dissertation | - |
dc.identifier.uri | http://hdl.handle.net/10203/32584 | - |
dc.description | 학위논문(석사) - 한국과학기술원 : 화학과, 1991.2, [ v, 44 p. ] | - |
dc.description.abstract | Di-or trialkyl phosphite reacted with tellurium(IV) chloride in methylene chloride at room temperature to give dialkyl chlorophosphate and elemental tellurium within a 10 minute. This reaction might proceed through penta-coordinate dihaplophosphite intermediate [$(RO)_3PCl_2$] which is immediately converted into dialkyl chlorophosphate by dealkylhalogenation. When tellurium(IV) chloride and trialkyl phosphite was reacted with nucleophiles such as alcohol and amine, the phosphorylation of nucleophiles readily occurred to give corresponding dialkyl organophosphates. | eng |
dc.language | eng | - |
dc.publisher | 한국과학기술원 | - |
dc.title | Synthesis of dialkyl chlorophosphate from Di- or trialkyl phosphite using tellurium(Ⅳ) chloride | - |
dc.title.alternative | 디- 또는 트리알킬 포스파이트로부터 사염화텔루르를 이용한 디알킬 클로로포스페이트의 합성 | - |
dc.type | Thesis(Master) | - |
dc.identifier.CNRN | 67612/325007 | - |
dc.description.department | 한국과학기술원 : 화학과, | - |
dc.identifier.uid | 000891013 | - |
dc.contributor.localauthor | Oh, Dong-Young | - |
dc.contributor.localauthor | 오동영 | - |
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