Study on the electronic and molecular structures of fluorocyclopropyl derivatives = 불소 시클로 유도체의 전자구조 및 분자구조의 연구

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The synthesis of 1,2-Dichlorodifluorocyclopropene had been carried out by the fluorination of tetrachlorocyclopropene. 1-Lithio-2-chlorodifluorocyclopropene was prepared through the lithium-chlorine exchange reaction with 1,2-Dichlorodifluorocyclopropene and n-Butyllithium. CNDO/2 calculation was carried out on hexafluorocyclopropane, tetrafluorocyclopropene, 1,2-Dichlorodifluorocycloprepene and 1-Lithio-2-chlorodiflurocyclopropene. A partial geometry optimization was carried out on 1-Lithio-2-chlorodifluorocyclopropene. We have obtained electronic structures, total energies, and dipole monents of these compounds.
Advisors
Choi, Sam-Kwon최삼권
Description
한국과학기술원 : 화학과,
Publisher
한국과학기술원
Issue Date
1980
Identifier
62581/325007 / 000781004
Language
eng
Description

학위논문 (석사) - 한국과학기술원 : 화학과, 1980.2, [ [ii], 38, [9] p. ]

URI
http://hdl.handle.net/10203/32249
Link
http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=62581&flag=dissertation
Appears in Collection
CH-Theses_Master(석사논문)
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