Neutron diffraction and X-ray absorption spectroscopic analyses for lithiated Aurivillius-type layered perovskite oxide, Li2Bi4Ti3O12

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dc.contributor.authorChoy, JHko
dc.contributor.authorKim, JYko
dc.contributor.authorChung, Iko
dc.date.accessioned2019-04-15T16:33:21Z-
dc.date.available2019-04-15T16:33:21Z-
dc.date.created2013-05-06-
dc.date.issued2001-08-
dc.identifier.citationJOURNAL OF PHYSICAL CHEMISTRY B, v.105, no.33, pp.7908 - 7912-
dc.identifier.issn1089-5647-
dc.identifier.urihttp://hdl.handle.net/10203/255933-
dc.description.abstractThe chemical lithiation of Aurivillius-type layered perovskite oxide, Bi4Ti3O12 (BTO), was demonstrated for the first time. The crystal and electronic structures of the lithiated BTO were characterized by neutron diffaction and X-ray absorption spectroscopic analyses. According to the neutron diffaction studies, it has been found that the lithium atoms are positioned between a perovskite block and a Bi2O2 layer. From the Bi L-III- and Ti K-edge XANES/EXAFS analyses, it has been found that significant amounts of Bi and Ti cations are reduced due to the Li-intercalation, and that the local structure around Ti becomes more distorted.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectVALENCE-
dc.subjectMULTILAYERS-
dc.subjectFILMS-
dc.titleNeutron diffraction and X-ray absorption spectroscopic analyses for lithiated Aurivillius-type layered perovskite oxide, Li2Bi4Ti3O12-
dc.typeArticle-
dc.identifier.wosid000170506800006-
dc.identifier.scopusid2-s2.0-0035940242-
dc.type.rimsART-
dc.citation.volume105-
dc.citation.issue33-
dc.citation.beginningpage7908-
dc.citation.endingpage7912-
dc.citation.publicationnameJOURNAL OF PHYSICAL CHEMISTRY B-
dc.identifier.doi10.1021/jp010895h-
dc.contributor.localauthorChung, I-
dc.contributor.nonIdAuthorChoy, JH-
dc.contributor.nonIdAuthorKim, JY-
dc.type.journalArticleArticle-
dc.subject.keywordPlusVALENCE-
dc.subject.keywordPlusMULTILAYERS-
dc.subject.keywordPlusFILMS-
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