DC Field | Value | Language |
---|---|---|
dc.contributor.author | Gu, Geun Ho | ko |
dc.contributor.author | Wittreich, Gerhard R. | ko |
dc.contributor.author | Vlachos, Dionisios G. | ko |
dc.date.accessioned | 2019-02-21T01:24:32Z | - |
dc.date.available | 2019-02-21T01:24:32Z | - |
dc.date.created | 2019-02-18 | - |
dc.date.issued | 2019-04 | - |
dc.identifier.citation | CHEMICAL ENGINEERING SCIENCE, v.197, pp.415 - 418 | - |
dc.identifier.issn | 0009-2509 | - |
dc.identifier.uri | http://hdl.handle.net/10203/250456 | - |
dc.description.abstract | In this communication, we develop automatically a reaction network for ethylene glycol reforming on Pt. We employ a recently introduced group additivity scheme for estimation of thermochemistry over metal catalysts in vapor phase and in solution along with Bronsted-Evans-Polanyi (BEP) relations for vapor phase kinetics to parameterize microkinetic models for vapor and aqueous phases. Unlike vapor-phase reforming, we show that solvent occupies a significant fraction of surface sites and by doing this, it shifts the water-gas shift reaction to CO2 and H-2 and avoids poisoning of the catalyst by CO. The model is found to be in reasonable agreement with the experimental data. (C) 2019 Elsevier Ltd. All rights reserved. | - |
dc.language | English | - |
dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | - |
dc.title | Microkinetic modeling of aqueous phase biomass conversion:Application to ethylene glycol reforming | - |
dc.type | Article | - |
dc.identifier.wosid | 000457634000038 | - |
dc.identifier.scopusid | 2-s2.0-85060307882 | - |
dc.type.rims | ART | - |
dc.citation.volume | 197 | - |
dc.citation.beginningpage | 415 | - |
dc.citation.endingpage | 418 | - |
dc.citation.publicationname | CHEMICAL ENGINEERING SCIENCE | - |
dc.identifier.doi | 10.1016/j.ces.2018.12.036 | - |
dc.contributor.localauthor | Gu, Geun Ho | - |
dc.contributor.nonIdAuthor | Wittreich, Gerhard R. | - |
dc.contributor.nonIdAuthor | Vlachos, Dionisios G. | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
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