DC Field | Value | Language |
---|---|---|
dc.contributor.author | Han, Sang Hoon | ko |
dc.contributor.author | Pandey, Ashok Kumar | ko |
dc.contributor.author | Lee, Heeyoung | ko |
dc.contributor.author | Kim, Saegun | ko |
dc.contributor.author | Kang, Dahye | ko |
dc.contributor.author | Jung, Young Hoon | ko |
dc.contributor.author | Kim, Hyung Sik | ko |
dc.contributor.author | Hong, Sungwoo | ko |
dc.contributor.author | Kim, In Su | ko |
dc.date.accessioned | 2018-12-20T01:47:25Z | - |
dc.date.available | 2018-12-20T01:47:25Z | - |
dc.date.created | 2018-11-26 | - |
dc.date.created | 2018-11-26 | - |
dc.date.issued | 2018-11 | - |
dc.identifier.citation | ORGANIC CHEMISTRY FRONTIERS, v.5, no.22 | - |
dc.identifier.issn | 2052-4129 | - |
dc.identifier.uri | http://hdl.handle.net/10203/247124 | - |
dc.description.abstract | The efficient synthesis of 2-naphthols is important for their further development as bioactive compounds and chiral ligands as well as other synthetic purposes. Herein, we describe the unprecedented one-pot synthesis of 2-naphthols through an acid-mediated decarboxylative N-O bond cleavage of bridged benzoxazepine intermediates, which were in turn generated from aryl nitrones and Morita-Baylis-Hillman (MBH) adducts under cationic rhodium(iii) catalysis. A range of 2-naphthol derivatives including anthracen-2-ol, phenanthren-2-ol, and 11H-benzo[b]fluoren-7-ol were formed with excellent site selectivities and functional group compatibilities. To gain mechanistic insight into this process, a series of mechanistic investigations and DFT calculations were also performed. | - |
dc.language | English | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.subject | C-H ACTIVATION | - |
dc.subject | BETA-HYDROXY KETONES | - |
dc.subject | ADDITION-DIECKMANN CONDENSATION | - |
dc.subject | CATALYZED HYDROXYLATION | - |
dc.subject | ASYMMETRIC CATALYSIS | - |
dc.subject | ARYL HALIDES | - |
dc.subject | MILD | - |
dc.subject | NEOCARZINOSTATIN | - |
dc.subject | CYCLOADDITION | - |
dc.subject | NAPHTHALENES | - |
dc.title | One-pot synthesis of 2-naphthols from nitrones and MBH adducts via decarboxylative N-O bond cleavage | - |
dc.type | Article | - |
dc.identifier.wosid | 000449412800002 | - |
dc.identifier.scopusid | 2-s2.0-85056223654 | - |
dc.type.rims | ART | - |
dc.citation.volume | 5 | - |
dc.citation.issue | 22 | - |
dc.citation.publicationname | ORGANIC CHEMISTRY FRONTIERS | - |
dc.identifier.doi | 10.1039/c8qo00988k | - |
dc.contributor.localauthor | Hong, Sungwoo | - |
dc.contributor.nonIdAuthor | Han, Sang Hoon | - |
dc.contributor.nonIdAuthor | Pandey, Ashok Kumar | - |
dc.contributor.nonIdAuthor | Lee, Heeyoung | - |
dc.contributor.nonIdAuthor | Kim, Saegun | - |
dc.contributor.nonIdAuthor | Jung, Young Hoon | - |
dc.contributor.nonIdAuthor | Kim, Hyung Sik | - |
dc.contributor.nonIdAuthor | Kim, In Su | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | C-H ACTIVATION | - |
dc.subject.keywordPlus | BETA-HYDROXY KETONES | - |
dc.subject.keywordPlus | ADDITION-DIECKMANN CONDENSATION | - |
dc.subject.keywordPlus | CATALYZED HYDROXYLATION | - |
dc.subject.keywordPlus | ASYMMETRIC CATALYSIS | - |
dc.subject.keywordPlus | ARYL HALIDES | - |
dc.subject.keywordPlus | MILD | - |
dc.subject.keywordPlus | NEOCARZINOSTATIN | - |
dc.subject.keywordPlus | CYCLOADDITION | - |
dc.subject.keywordPlus | NAPHTHALENES | - |
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