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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Reactivity of Morita-Baylis-Hillman Adducts in C-H Functionalization of (Hetero)aryl Nitrones: Access to Bridged Cycles and Carbazoles

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dc.contributor.authorPandey, Ashok Kumarko
dc.contributor.authorKang, Dahyeko
dc.contributor.authorHan, Sang Hoonko
dc.contributor.authorLee, Heeyoungko
dc.contributor.authorMishra, Neeraj Kumarko
dc.contributor.authorKim, Hyung Sikko
dc.contributor.authorJung, Young Hoonko
dc.contributor.authorHong, Sungwooko
dc.contributor.authorKim, In Suko
dc.date.accessioned2018-09-18T06:24:03Z-
dc.date.available2018-09-18T06:24:03Z-
dc.date.created2018-09-04-
dc.date.created2018-09-04-
dc.date.issued2018-08-
dc.identifier.citationORGANIC LETTERS, v.20, no.15, pp.4632 - 4636-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10203/245572-
dc.description.abstractThe rhodium(III)-catalyzed cross-coupling of (hetero)aryl nitrones with Morita-Baylis-Hillman (MBH) adducts is described. An allylated intermediate derived from aryl nitrones and MBH adducts allows the formation of bridged cyclic compounds via an exotype [3 + 2] cycloaddition. In sharp contrast, electron-rich indolinyl or aniline substrates were found to couple with MBH adducts to generate naphthalene or carbazole derivatives, respectively.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectN-HETEROCYCLES-
dc.subjectACTIVATION-
dc.subjectALLYLATION-
dc.subjectALKYNES-
dc.subjectARYLNITRONES-
dc.subjectCYCLIZATION-
dc.subjectANNULATION-
dc.subjectCATALYSIS-
dc.subjectINDOLES-
dc.subjectARENES-
dc.titleReactivity of Morita-Baylis-Hillman Adducts in C-H Functionalization of (Hetero)aryl Nitrones: Access to Bridged Cycles and Carbazoles-
dc.typeArticle-
dc.identifier.wosid000441112700055-
dc.identifier.scopusid2-s2.0-85050984479-
dc.type.rimsART-
dc.citation.volume20-
dc.citation.issue15-
dc.citation.beginningpage4632-
dc.citation.endingpage4636-
dc.citation.publicationnameORGANIC LETTERS-
dc.identifier.doi10.1021/acs.orglett.8b01910-
dc.contributor.localauthorHong, Sungwoo-
dc.contributor.nonIdAuthorPandey, Ashok Kumar-
dc.contributor.nonIdAuthorHan, Sang Hoon-
dc.contributor.nonIdAuthorLee, Heeyoung-
dc.contributor.nonIdAuthorMishra, Neeraj Kumar-
dc.contributor.nonIdAuthorKim, Hyung Sik-
dc.contributor.nonIdAuthorJung, Young Hoon-
dc.contributor.nonIdAuthorKim, In Su-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordPlusN-HETEROCYCLES-
dc.subject.keywordPlusACTIVATION-
dc.subject.keywordPlusALLYLATION-
dc.subject.keywordPlusALKYNES-
dc.subject.keywordPlusARYLNITRONES-
dc.subject.keywordPlusCYCLIZATION-
dc.subject.keywordPlusANNULATION-
dc.subject.keywordPlusCATALYSIS-
dc.subject.keywordPlusINDOLES-
dc.subject.keywordPlusARENES-
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CH-Journal Papers(저널논문)
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