DC Field | Value | Language |
---|---|---|
dc.contributor.author | Pandey, Ashok Kumar | ko |
dc.contributor.author | Han, Sang Hoon | ko |
dc.contributor.author | Mishra, Neeraj Kumar | ko |
dc.contributor.author | Kang, Dahye | ko |
dc.contributor.author | Lee, Suk Hun | ko |
dc.contributor.author | Chun, Rina | ko |
dc.contributor.author | Hong, Sungwoo | ko |
dc.contributor.author | Park, Jung Su | ko |
dc.contributor.author | Kim, In Su | ko |
dc.date.accessioned | 2018-02-21T05:53:43Z | - |
dc.date.available | 2018-02-21T05:53:43Z | - |
dc.date.created | 2018-02-05 | - |
dc.date.created | 2018-02-05 | - |
dc.date.issued | 2018-01 | - |
dc.identifier.citation | ACS CATALYSIS, v.8, no.1, pp.742 - 746 | - |
dc.identifier.issn | 2155-5435 | - |
dc.identifier.uri | http://hdl.handle.net/10203/240159 | - |
dc.description.abstract | The rhodium(III)-catalyzed cross-coupling reaction between commercially available benzylamines and Morita-Baylis--Hillman (MBH) adducts is described. This protocol provides a facile access to various 2-benzazepine derivatives via the C(sp(2))-H activation of N-allylated benzylamines and subsequent intramolecular olefin insertion followed by N-allylation reaction. A range of substrates has been used, and a high level of chemoselectivity as well as functional group tolerance was observed. To gain mechanistic insight of this transformation, DFT performed. calculations were also performed. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | BAYLIS-HILLMAN ADDUCTS | - |
dc.subject | C-H ACTIVATION | - |
dc.subject | DENSITY FUNCTIONALS | - |
dc.subject | BIOLOGICAL-ACTIVITY | - |
dc.subject | BOND-CLEAVAGE | - |
dc.subject | AZOBENZENES | - |
dc.subject | CYCLIZATION | - |
dc.subject | ALKENYLATION | - |
dc.subject | DERIVATIVES | - |
dc.subject | ALKYLATION | - |
dc.title | Synthesis of 2-Benzazepines from Benzylamines and MBH Adducts Under Rhodium(III) Catalysis via C(sp(2))-H Functionalization | - |
dc.type | Article | - |
dc.identifier.wosid | 000419751100078 | - |
dc.identifier.scopusid | 2-s2.0-85040310648 | - |
dc.type.rims | ART | - |
dc.citation.volume | 8 | - |
dc.citation.issue | 1 | - |
dc.citation.beginningpage | 742 | - |
dc.citation.endingpage | 746 | - |
dc.citation.publicationname | ACS CATALYSIS | - |
dc.identifier.doi | 10.1021/acscatal.7b03812 | - |
dc.contributor.localauthor | Hong, Sungwoo | - |
dc.contributor.nonIdAuthor | Pandey, Ashok Kumar | - |
dc.contributor.nonIdAuthor | Han, Sang Hoon | - |
dc.contributor.nonIdAuthor | Mishra, Neeraj Kumar | - |
dc.contributor.nonIdAuthor | Lee, Suk Hun | - |
dc.contributor.nonIdAuthor | Chun, Rina | - |
dc.contributor.nonIdAuthor | Park, Jung Su | - |
dc.contributor.nonIdAuthor | Kim, In Su | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | benzazepines | - |
dc.subject.keywordAuthor | benzylamines | - |
dc.subject.keywordAuthor | C-H activation | - |
dc.subject.keywordAuthor | Morita-Baylis-Hillman adducts | - |
dc.subject.keywordAuthor | rhodium | - |
dc.subject.keywordPlus | BAYLIS-HILLMAN ADDUCTS | - |
dc.subject.keywordPlus | C-H ACTIVATION | - |
dc.subject.keywordPlus | DENSITY FUNCTIONALS | - |
dc.subject.keywordPlus | BIOLOGICAL-ACTIVITY | - |
dc.subject.keywordPlus | BOND-CLEAVAGE | - |
dc.subject.keywordPlus | AZOBENZENES | - |
dc.subject.keywordPlus | CYCLIZATION | - |
dc.subject.keywordPlus | ALKENYLATION | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | ALKYLATION | - |
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