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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Synthesis of 2-Benzazepines from Benzylamines and MBH Adducts Under Rhodium(III) Catalysis via C(sp(2))-H Functionalization

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dc.contributor.authorPandey, Ashok Kumarko
dc.contributor.authorHan, Sang Hoonko
dc.contributor.authorMishra, Neeraj Kumarko
dc.contributor.authorKang, Dahyeko
dc.contributor.authorLee, Suk Hunko
dc.contributor.authorChun, Rinako
dc.contributor.authorHong, Sungwooko
dc.contributor.authorPark, Jung Suko
dc.contributor.authorKim, In Suko
dc.date.accessioned2018-02-21T05:53:43Z-
dc.date.available2018-02-21T05:53:43Z-
dc.date.created2018-02-05-
dc.date.created2018-02-05-
dc.date.issued2018-01-
dc.identifier.citationACS CATALYSIS, v.8, no.1, pp.742 - 746-
dc.identifier.issn2155-5435-
dc.identifier.urihttp://hdl.handle.net/10203/240159-
dc.description.abstractThe rhodium(III)-catalyzed cross-coupling reaction between commercially available benzylamines and Morita-Baylis--Hillman (MBH) adducts is described. This protocol provides a facile access to various 2-benzazepine derivatives via the C(sp(2))-H activation of N-allylated benzylamines and subsequent intramolecular olefin insertion followed by N-allylation reaction. A range of substrates has been used, and a high level of chemoselectivity as well as functional group tolerance was observed. To gain mechanistic insight of this transformation, DFT performed. calculations were also performed.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectBAYLIS-HILLMAN ADDUCTS-
dc.subjectC-H ACTIVATION-
dc.subjectDENSITY FUNCTIONALS-
dc.subjectBIOLOGICAL-ACTIVITY-
dc.subjectBOND-CLEAVAGE-
dc.subjectAZOBENZENES-
dc.subjectCYCLIZATION-
dc.subjectALKENYLATION-
dc.subjectDERIVATIVES-
dc.subjectALKYLATION-
dc.titleSynthesis of 2-Benzazepines from Benzylamines and MBH Adducts Under Rhodium(III) Catalysis via C(sp(2))-H Functionalization-
dc.typeArticle-
dc.identifier.wosid000419751100078-
dc.identifier.scopusid2-s2.0-85040310648-
dc.type.rimsART-
dc.citation.volume8-
dc.citation.issue1-
dc.citation.beginningpage742-
dc.citation.endingpage746-
dc.citation.publicationnameACS CATALYSIS-
dc.identifier.doi10.1021/acscatal.7b03812-
dc.contributor.localauthorHong, Sungwoo-
dc.contributor.nonIdAuthorPandey, Ashok Kumar-
dc.contributor.nonIdAuthorHan, Sang Hoon-
dc.contributor.nonIdAuthorMishra, Neeraj Kumar-
dc.contributor.nonIdAuthorLee, Suk Hun-
dc.contributor.nonIdAuthorChun, Rina-
dc.contributor.nonIdAuthorPark, Jung Su-
dc.contributor.nonIdAuthorKim, In Su-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorbenzazepines-
dc.subject.keywordAuthorbenzylamines-
dc.subject.keywordAuthorC-H activation-
dc.subject.keywordAuthorMorita-Baylis-Hillman adducts-
dc.subject.keywordAuthorrhodium-
dc.subject.keywordPlusBAYLIS-HILLMAN ADDUCTS-
dc.subject.keywordPlusC-H ACTIVATION-
dc.subject.keywordPlusDENSITY FUNCTIONALS-
dc.subject.keywordPlusBIOLOGICAL-ACTIVITY-
dc.subject.keywordPlusBOND-CLEAVAGE-
dc.subject.keywordPlusAZOBENZENES-
dc.subject.keywordPlusCYCLIZATION-
dc.subject.keywordPlusALKENYLATION-
dc.subject.keywordPlusDERIVATIVES-
dc.subject.keywordPlusALKYLATION-
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