Metal- and oxidant-free S-P(O) bond construction via direct coupling of P(O) H with sulfinic acids

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We have developed a simple and convenient method for S-P(O) bond formation between R2P(O) H and sulfinic acids under metal-, oxidant-, and halogen-free conditions. The current method is compatible with a broad range of substituents on various substrates including halogens and heterocyclic moieties. The synthetic potential of this method was further highlighted by the expeditious synthesis of optically active P-chiral phosphorothioates via stereospecific coupling.
Publisher
ROYAL SOC CHEMISTRY
Issue Date
2017-02
Language
English
Article Type
Article
Keywords

ARYLSULFINIC ACIDS; AEROBIC DIFUNCTIONALIZATION; ALLYLIC SULFONES; PHOSPHINE OXIDES; HIGHLY EFFICIENT; VINYL SULFONES; GENERAL-METHOD; S-ARYL; DERIVATIVES; ALKYNES

Citation

GREEN CHEMISTRY, v.19, no.4, pp.1005 - 1013

ISSN
1463-9262
DOI
10.1039/c6gc03285k
URI
http://hdl.handle.net/10203/223027
Appears in Collection
CH-Journal Papers(저널논문)
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