Real nerve agent study assessing pyridyl reactivity: Selective fluorogenic and colorimetric detection of Soman and simulant

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Herein, a chemical probe is tested with live agents for the purpose of benchmarking fluorescent pyridyl-containing systems with actual nerve agents and simulants together. The molecule showed selective fluorogenic and colorimetric detection of Soman (GD) and its simulant over other G-series nerve agents and their simulants. H-1 and P-31 NMR spectroscopy and TD-DFT calculations help reveal the origin of the colorimetric and fluorogenic changes in the reacted system. (C) 2016 Elsevier B.V. All rights reserved.
Publisher
ELSEVIER SCIENCE SA
Issue Date
2017-02
Language
English
Article Type
Article
Keywords

CHEMICAL WARFARE AGENTS; DEGRADATION-PRODUCTS; MIMICS; DISCRIMINATION; DCNP; DCP; SPECTROMETRY; ENHANCEMENT; LIQUID

Citation

SENSORS AND ACTUATORS B-CHEMICAL, v.238, pp.145 - 149

ISSN
0925-4005
DOI
10.1016/j.snb.2016.07.056
URI
http://hdl.handle.net/10203/220108
Appears in Collection
CH-Journal Papers(저널논문)
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