DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, Kang Mun | ko |
dc.contributor.author | Ryu, Ji Yeon | ko |
dc.contributor.author | Park, Yu Jin | ko |
dc.contributor.author | Churchill, David G | ko |
dc.contributor.author | Kim, Youngjo | ko |
dc.contributor.author | Lee, Junseong | ko |
dc.date.accessioned | 2016-11-09T08:23:53Z | - |
dc.date.available | 2016-11-09T08:23:53Z | - |
dc.date.created | 2016-10-31 | - |
dc.date.created | 2016-10-31 | - |
dc.date.issued | 2016-10 | - |
dc.identifier.citation | POLYHEDRON, v.117, pp.735 - 740 | - |
dc.identifier.issn | 0277-5387 | - |
dc.identifier.uri | http://hdl.handle.net/10203/213984 | - |
dc.description.abstract | Herein, we report various metal complexes containing {5-(2-hydroxy)phenyl}tetrazolyl (H(2)hptz) which form various high-dimensional coordination polymers in a crystalline solid state. A reaction of metal per chlorates, 2,2'-bipyrimidine (bpym), KOH, and tetrazolyl ligand (H(2)hptz) in H2O or N,N-dimethylmethanamide (DMF) yield 2-D [Cu(hptz)(bpym)](n) (1), [Zn(hptz)(bpym)](n) (2) and 3-D [K(bpym)(2)Ni(hptz) (H2O)(2.5)(OH)](n) (3) coordination complexes with a high synthetic yield. These compounds were characterized by elemental analysis, IR spectroscopy, and single crystal X-ray crystallography. Cu2+ and Zn2+ complexes showed 2-D infinite network systems, forming coordination polymers (caused by extra bonding between metal ions and tetrazolyl). The environment of the Cu and Zn metal centers are quite similar; however, Zn2+ complexes have significantly shorter Zn-O bond distances with the hydroxyl group of other [Zn(hptz)(bpym)] unit. The Ni2+ complex 3 showed a completely different composition from that of complexes 1-2. Complex 3 showed 3-D structure based on octahedral units, which were composed of two hptz(2-) and one bpym ligands around the Ni center. These units infinitely repeat with K ions and water molecules along the a-, b-, and c-axes of the unit cells. Their magnetic behaviors were also studied. (C) 2016 Elsevier Ltd. All rights reserved | - |
dc.language | English | - |
dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | - |
dc.subject | IN-SITU FORMATION | - |
dc.subject | SUPRAMOLECULAR ARCHITECTURES | - |
dc.subject | CRYSTAL-STRUCTURES | - |
dc.subject | COMPLEXES | - |
dc.subject | CYCLOADDITION | - |
dc.subject | MONONUCLEAR | - |
dc.subject | FRAMEWORKS | - |
dc.subject | MN(II) | - |
dc.subject | ZN | - |
dc.subject | CO | - |
dc.title | Copper(II), zinc(II) and nickel(II) coordination polymers using bidentate hyroxyphenyl-tetrazolyl ligand | - |
dc.type | Article | - |
dc.identifier.wosid | 000384384500088 | - |
dc.identifier.scopusid | 2-s2.0-84980322923 | - |
dc.type.rims | ART | - |
dc.citation.volume | 117 | - |
dc.citation.beginningpage | 735 | - |
dc.citation.endingpage | 740 | - |
dc.citation.publicationname | POLYHEDRON | - |
dc.identifier.doi | 10.1016/j.poly.2016.06.051 | - |
dc.contributor.localauthor | Churchill, David G | - |
dc.contributor.nonIdAuthor | Lee, Kang Mun | - |
dc.contributor.nonIdAuthor | Ryu, Ji Yeon | - |
dc.contributor.nonIdAuthor | Park, Yu Jin | - |
dc.contributor.nonIdAuthor | Kim, Youngjo | - |
dc.contributor.nonIdAuthor | Lee, Junseong | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | Tetrazole | - |
dc.subject.keywordAuthor | Coordination polymer | - |
dc.subject.keywordAuthor | X-ray structure | - |
dc.subject.keywordAuthor | Bipyrimidine | - |
dc.subject.keywordAuthor | Bidentate ligand | - |
dc.subject.keywordPlus | IN-SITU FORMATION | - |
dc.subject.keywordPlus | SUPRAMOLECULAR ARCHITECTURES | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURES | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | CYCLOADDITION | - |
dc.subject.keywordPlus | MONONUCLEAR | - |
dc.subject.keywordPlus | FRAMEWORKS | - |
dc.subject.keywordPlus | MN(II) | - |
dc.subject.keywordPlus | ZN | - |
dc.subject.keywordPlus | CO | - |
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