Palladium(II)-Catalyzed Tandem Synthesis of Acenes Using Carboxylic Acids as Traceless Directing Groups

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A straightforward synthetic strategy for generating useful anthracene derivatives was developed involving palladium(II)-catalyzed tandem transformation with carboxylic acids as traceless directing groups. Carboxyl-directed C-H alkenylation, carboxyl-directed secondary C-H activation and rollover, intramolecular C-C bond formation, and decarboxylative aromatization are proposed as the key steps in the tandem reaction pathway. This novel synthetic route utilizes a broad range of substrates and provides a convenient synthetic tool that allows access to acenes
Publisher
WILEY-V C H VERLAG GMBH
Issue Date
2016-07
Language
English
Article Type
Article
Keywords

H BOND ACTIVATION; POLYCYCLIC AROMATIC-COMPOUNDS; DIELS-ALDER REACTIONS; C-H; BENZOIC-ACIDS; DIRECT ARYLATION; PALLADIUM; CATALYSIS; CYCLIZATION; FUNCTIONALIZATION

Citation

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.55, no.30, pp.8652 - 8655

ISSN
1433-7851
DOI
10.1002/anie.201603661
URI
http://hdl.handle.net/10203/213607
Appears in Collection
CH-Journal Papers(저널논문)
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