Tailoring open metal sites for selective capture of CO2 in isostructural metalloporphyrin porous organic networks

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Porphyrin-based isostructural porous organic networks have been synthesized by varying the central metal atoms to cobalt, nickel and copper. Their selectivities for CO2 capture over N-2 and Ar are found to be enhanced as the heats of adsorption for CO2 are increased in the order of Co, Ni and Cu, while the pore structures are well maintained.
Publisher
ROYAL SOC CHEMISTRY
Issue Date
2015-12
Language
English
Article Type
Article
Citation

NANOSCALE, v.7, no.45, pp.18923 - 18927

ISSN
2040-3364
DOI
10.1039/c5nr05696a
URI
http://hdl.handle.net/10203/207866
Appears in Collection
EEW-Journal Papers(저널논문)
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