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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Asymmetric C-H functionalization of cyclopropanes using an isoleucine-NH2 bidentate directing group

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dc.contributor.authorKim, Jin Heeko
dc.contributor.authorSim, Mikyungko
dc.contributor.authorKim, Namhoonko
dc.contributor.authorHong, Sung-Wooko
dc.date.accessioned2015-06-25T06:34:31Z-
dc.date.available2015-06-25T06:34:31Z-
dc.date.created2015-06-16-
dc.date.created2015-06-16-
dc.date.created2015-06-16-
dc.date.created2015-06-16-
dc.date.issued2015-05-
dc.identifier.citationCHEMICAL SCIENCE, v.6, no.6, pp.3611 - 3616-
dc.identifier.issn2041-6520-
dc.identifier.urihttp://hdl.handle.net/10203/199100-
dc.description.abstractThe systematic investigation of substrate-bound alpha-amino acid auxiliaries has resulted in catalytic asymmetric C-H functionalization of cyclopropanes enabled by amino acid amides as chiral bidentate directing groups. The use of an Ile-NH2 auxiliary embedded in the substrate provided excellent levels of asymmetric induction (diastereomeric ratio of up to 72:1) in the Pd(II)-catalyzed beta-methylene C(sp(3))-H bond activation of cyclopropanes and cross-coupling with aryl iodides.-
dc.languageEnglish-
dc.publisherROYAL SOC CHEMISTRY-
dc.titleAsymmetric C-H functionalization of cyclopropanes using an isoleucine-NH2 bidentate directing group-
dc.typeArticle-
dc.identifier.wosid000354815600046-
dc.identifier.scopusid2-s2.0-84929598029-
dc.type.rimsART-
dc.citation.volume6-
dc.citation.issue6-
dc.citation.beginningpage3611-
dc.citation.endingpage3616-
dc.citation.publicationnameCHEMICAL SCIENCE-
dc.identifier.doi10.1039/c5sc01137j-
dc.contributor.localauthorHong, Sung-Woo-
dc.contributor.nonIdAuthorKim, Namhoon-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordPlusCATALYZED DIRECT ARYLATION-
dc.subject.keywordPlusUNACTIVATED C(SP(3))-H BONDS-
dc.subject.keywordPlusCARBON-HYDROGEN BONDS-
dc.subject.keywordPlusACID-DERIVATIVES-
dc.subject.keywordPlusCOUPLING REACTIONS-
dc.subject.keywordPlusCHELATION ASSISTANCE-
dc.subject.keywordPlusAROMATIC AMIDES-
dc.subject.keywordPlusMILD CONDITIONS-
dc.subject.keywordPlusALKYL-HALIDES-
dc.subject.keywordPlusACTIVATION-
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CH-Journal Papers(저널논문)
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