DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, Jin Hee | ko |
dc.contributor.author | Heo, Jaewon | ko |
dc.contributor.author | Park, Chang Jun | ko |
dc.contributor.author | Kim, Byung-kwon | ko |
dc.contributor.author | Kwak, Ju-Hyoun | ko |
dc.contributor.author | Seo, Myungeun | ko |
dc.contributor.author | Kim, Sang Youl | ko |
dc.date.accessioned | 2015-03-26T08:17:49Z | - |
dc.date.available | 2015-03-26T08:17:49Z | - |
dc.date.created | 2014-09-30 | - |
dc.date.created | 2014-09-30 | - |
dc.date.issued | 2014-09 | - |
dc.identifier.citation | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, v.52, no.18, pp.2692 - 2702 | - |
dc.identifier.issn | 0887-624X | - |
dc.identifier.uri | http://hdl.handle.net/10203/194156 | - |
dc.description.abstract | We report synthesis of a series of new triarylamine-containing AB-type monomers and their polymers via nucleophilic aromatic substitution (SNAr) reaction. Monomers consisting of a hydroxyl group at the para position of the nitrogen group in one phenyl ring and a fluorine leaving group at the para position in another phenyl ring were synthesized via palladium-catalyzed amination reaction. The fluorine leaving group was activated by trifluoromethyl group at the ortho position and an electron-withdrawing group (EWG) introduced at the para position of the unsubstituted phenyl ring that enabled control over monomer reactivity. SNAr reaction of the monomers successfully produced corresponding poly(arylene ether)s with pendant EWGs that exhibited good solubility and thermal stability. Optical and electrochemical properties of the polymers were also affected by incorporation of EWGs. | - |
dc.language | English | - |
dc.publisher | WILEY-BLACKWELL | - |
dc.subject | NITRO DISPLACEMENT REACTION | - |
dc.subject | NONLINEAR-OPTICAL CHROMOPHORES | - |
dc.subject | FIELD-EFFECT TRANSISTORS | - |
dc.subject | LIGHT-EMITTING-DIODES | - |
dc.subject | AB-TYPE MONOMERS | - |
dc.subject | ELECTROLUMINESCENT DEVICES | - |
dc.subject | POLY(BIPHENYLENE OXIDE)S | - |
dc.subject | TRIFLUOROMETHYL GROUPS | - |
dc.subject | THERMAL-STABILITY | - |
dc.subject | TRIPHENYLAMINE UNITS | - |
dc.title | Synthesis of Triarylamine-Containing Poly(arylene ether)s by Nucleophilic Aromatic Substitution Reaction | - |
dc.type | Article | - |
dc.identifier.wosid | 000341189900015 | - |
dc.identifier.scopusid | 2-s2.0-84906101523 | - |
dc.type.rims | ART | - |
dc.citation.volume | 52 | - |
dc.citation.issue | 18 | - |
dc.citation.beginningpage | 2692 | - |
dc.citation.endingpage | 2702 | - |
dc.citation.publicationname | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | - |
dc.identifier.doi | 10.1002/pola.27289 | - |
dc.contributor.localauthor | Kwak, Ju-Hyoun | - |
dc.contributor.localauthor | Seo, Myungeun | - |
dc.contributor.localauthor | Kim, Sang Youl | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | high performance polymers | - |
dc.subject.keywordAuthor | nucleophilic aromatic substitution reaction | - |
dc.subject.keywordAuthor | polycondensation | - |
dc.subject.keywordAuthor | polyethers | - |
dc.subject.keywordAuthor | triarylamine | - |
dc.subject.keywordPlus | NITRO DISPLACEMENT REACTION | - |
dc.subject.keywordPlus | NONLINEAR-OPTICAL CHROMOPHORES | - |
dc.subject.keywordPlus | FIELD-EFFECT TRANSISTORS | - |
dc.subject.keywordPlus | LIGHT-EMITTING-DIODES | - |
dc.subject.keywordPlus | AB-TYPE MONOMERS | - |
dc.subject.keywordPlus | ELECTROLUMINESCENT DEVICES | - |
dc.subject.keywordPlus | POLY(BIPHENYLENE OXIDE)S | - |
dc.subject.keywordPlus | TRIFLUOROMETHYL GROUPS | - |
dc.subject.keywordPlus | THERMAL-STABILITY | - |
dc.subject.keywordPlus | TRIPHENYLAMINE UNITS | - |
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