DC Field | Value | Language |
---|---|---|
dc.contributor.author | Jeon, Min-Ku | ko |
dc.contributor.author | Won, Jung-Yeon | ko |
dc.contributor.author | Lee, Ki-Rak | ko |
dc.contributor.author | Woo, Seong-Ihl | ko |
dc.date.accessioned | 2010-05-13T02:46:25Z | - |
dc.date.available | 2010-05-13T02:46:25Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2007-09 | - |
dc.identifier.citation | ELECTROCHEMISTRY COMMUNICATIONS, v.9, no.9, pp.2163 - 2166 | - |
dc.identifier.issn | 1388-2481 | - |
dc.identifier.uri | http://hdl.handle.net/10203/18268 | - |
dc.description.abstract | High methanol electro-oxidation activity was obtained on novel PtRuFe/C (2:1:1 at.%) catalyst. Mass and specific activities were 5.67 A g(-1) catal. and 177 mA m(-2) for the PtRuFe/C catalyst while those of the commercial PtRu/C catalyst were 2.28 A g(-1) catal. and 87.7 mA m(-2), respectively. CO stripping results showed that on-set voltage for CO electro-oxidation was lowered by incorporation of Fe. XRD and XPS results revealed that Fe2O3 was formed instead of Fe(0), which resulted in large electron deficiency in Pt and easy CO electro-oxidation. The electron deficiency of Pt was proved by XPS results of Pt4f peaks, which moved to higher binding energies in PtRuFe/C than PtRu/C. (c) 2007 Elsevier B.V. All rights reserved. | - |
dc.description.sponsorship | This work was funded by Center for Ultramicrochemical Process Systems (CUPS) sponsored by KOSEF (2007). The authors are thankful to H. Daimon and A. Nakahara in Hitachi Maxell Ltd. for their assistance in TEM measurement and Dr. D. H. Jung and his team in Korea Institute of Energy Research (KIER) for their guidance in synthesis and analysis of the catalyst. | en |
dc.language | English | - |
dc.language.iso | en_US | en |
dc.publisher | ELSEVIER SCIENCE INC | - |
dc.subject | FE ALLOY ELECTRODE | - |
dc.subject | COMBINATORIAL ELECTROCHEMISTRY | - |
dc.subject | FUEL-CELLS | - |
dc.subject | OXIDATION | - |
dc.subject | ELECTROCATALYSTS | - |
dc.subject | NANOPARTICLES | - |
dc.subject | ACID | - |
dc.subject | CO | - |
dc.title | Highly active PtRuFe/C catalyst for methanol electro-oxidation | - |
dc.type | Article | - |
dc.identifier.wosid | 000249798600003 | - |
dc.identifier.scopusid | 2-s2.0-34547941214 | - |
dc.type.rims | ART | - |
dc.citation.volume | 9 | - |
dc.citation.issue | 9 | - |
dc.citation.beginningpage | 2163 | - |
dc.citation.endingpage | 2166 | - |
dc.citation.publicationname | ELECTROCHEMISTRY COMMUNICATIONS | - |
dc.identifier.doi | 10.1016/j.elecom.2007.06.014 | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Woo, Seong-Ihl | - |
dc.contributor.nonIdAuthor | Jeon, Min-Ku | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | methanol electro-oxidation | - |
dc.subject.keywordAuthor | electrocatalysis | - |
dc.subject.keywordAuthor | direct methanol fuel cell | - |
dc.subject.keywordAuthor | CO stripping | - |
dc.subject.keywordAuthor | cyclic voltammetry | - |
dc.subject.keywordPlus | FE ALLOY ELECTRODE | - |
dc.subject.keywordPlus | COMBINATORIAL ELECTROCHEMISTRY | - |
dc.subject.keywordPlus | FUEL-CELLS | - |
dc.subject.keywordPlus | OXIDATION | - |
dc.subject.keywordPlus | ELECTROCATALYSTS | - |
dc.subject.keywordPlus | NANOPARTICLES | - |
dc.subject.keywordPlus | ACID | - |
dc.subject.keywordPlus | CO | - |
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