DC Field | Value | Language |
---|---|---|
dc.contributor.author | Zhang, Junshe | ko |
dc.contributor.author | Zhao, Yu | ko |
dc.contributor.author | Akins, Daniel L. | ko |
dc.contributor.author | Lee, Jae Woo | ko |
dc.date.accessioned | 2013-08-08T06:08:05Z | - |
dc.date.available | 2013-08-08T06:08:05Z | - |
dc.date.created | 2013-06-21 | - |
dc.date.issued | 2011-04 | - |
dc.identifier.citation | JOURNAL OF PHYSICAL CHEMISTRY C, v.115, no.16, pp.8386 - 8392 | - |
dc.identifier.issn | 1932-7447 | - |
dc.identifier.uri | http://hdl.handle.net/10203/174964 | - |
dc.description.abstract | This work presents the accelerated dehydrogenation of ammonia borane (AB) at 85 degrees C under carbon dioxide atmosphere. The presence of CO2 significantly enhances the thermolysis kinetics, and the hydrogen release becomes faster as the: CO2 pressure increases from 1.70 to 3.67 bar. Around 4 bar of CO2, 1.33 equiv of hydrogen is released from AB in 1 h. The accelerated AB thermolysis is due to CO2 reacting with AB, or intermediates like diammoniate of diborane (DADB), or primary thermolysis products including linear dimers of aminoborane (LDAB), which accelerates AB thermolysis, and this reaction has been confirmed by ATR-FTIR, Raman, and B-11 and C-13 solid-state MAS NMR measurements. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | CHEMICAL HYDROGEN STORAGE | - |
dc.subject | N-H COMPOUNDS | - |
dc.subject | THERMAL-DECOMPOSITION | - |
dc.subject | CATALYZED DEHYDROGENATION | - |
dc.subject | GENERATION | - |
dc.subject | NMR | - |
dc.subject | METHANOLYSIS | - |
dc.subject | DERIVATIVES | - |
dc.subject | FRAMEWORK | - |
dc.subject | SPECTRA | - |
dc.title | CO2-Enhanced Thermolytic H-2 Release from Ammonia Borane | - |
dc.type | Article | - |
dc.identifier.wosid | 000289697400069 | - |
dc.identifier.scopusid | 2-s2.0-79955399044 | - |
dc.type.rims | ART | - |
dc.citation.volume | 115 | - |
dc.citation.issue | 16 | - |
dc.citation.beginningpage | 8386 | - |
dc.citation.endingpage | 8392 | - |
dc.citation.publicationname | JOURNAL OF PHYSICAL CHEMISTRY C | - |
dc.identifier.doi | 10.1021/jp200049y | - |
dc.contributor.localauthor | Lee, Jae Woo | - |
dc.contributor.nonIdAuthor | Zhang, Junshe | - |
dc.contributor.nonIdAuthor | Zhao, Yu | - |
dc.contributor.nonIdAuthor | Akins, Daniel L. | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | CHEMICAL HYDROGEN STORAGE | - |
dc.subject.keywordPlus | N-H COMPOUNDS | - |
dc.subject.keywordPlus | THERMAL-DECOMPOSITION | - |
dc.subject.keywordPlus | CATALYZED DEHYDROGENATION | - |
dc.subject.keywordPlus | GENERATION | - |
dc.subject.keywordPlus | NMR | - |
dc.subject.keywordPlus | METHANOLYSIS | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | FRAMEWORK | - |
dc.subject.keywordPlus | SPECTRA | - |
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