Total synthesis of (-)-kaitocephalin

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(-)-Kaitocephalin has been synthesized. With the C9 stereocenter from Garner's aldehyde, the C4 quaternary carbon was installed by the desymmetrization of the Cbz-protected serinol. The remaining stereogenic centers were generated through mercuriocyclization, epoxidation and regioselective epoxide opening, in which the quaternary carbon most likely played crucial roles in the stereoinduction.
Publisher
ROYAL SOC CHEMISTRY
Issue Date
2013
Language
English
Article Type
Article
Keywords

RECEPTOR ANTAGONIST; KAITOCEPHALIN; ALCOHOLS; REVISION; ACID

Citation

CHEMICAL COMMUNICATIONS, v.49, no.45, pp.5231 - 5233

ISSN
1359-7345
DOI
10.1039/c3cc42365d
URI
http://hdl.handle.net/10203/174924
Appears in Collection
CH-Journal Papers(저널논문)
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