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College of Natural Sciences(자연과학대학)Graduate School of Nanoscience and Technology(나노과학기술대학원)NT-Journal Papers(저널논문)

Semiconducting [(Bi4Te4Br2)(Al2Cl6-xBrx)]Cl-2 and [Bi2Se2Br](AlCl4): Cationic Chalcogenide Frameworks from Lewis Acidic Ionic Liquids

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dc.contributor.authorBiswas, Kanishkako
dc.contributor.authorChung, Inko
dc.contributor.authorSong, Jung-Hwanko
dc.contributor.authorMalliakas, Christos D.ko
dc.contributor.authorFreeman, Arthur J.ko
dc.contributor.authorKanatzidis, Mercouri G.ko
dc.date.accessioned2013-08-08T02:31:57Z-
dc.date.available2013-08-08T02:31:57Z-
dc.date.created2013-08-07-
dc.date.created2013-08-07-
dc.date.created2013-08-07-
dc.date.issued2013-05-
dc.identifier.citationINORGANIC CHEMISTRY, v.52, no.10, pp.5657 - 5659-
dc.identifier.issn0020-1669-
dc.identifier.urihttp://hdl.handle.net/10203/174216-
dc.description.abstractLewis acidic organic ionic liquids provide a novel synthetic medium to prepare new semiconducting chalcogenides, [(Bi4Te4Br2)(Al2Cl5.46Br0.54)]Cl-2 (1) and [Bi2Se2Br](AlCl4) (2). Compound 1 features a cationic [(Bi4Te4Br2)(Al2Cl5.46Br0.54)](2+) three-dimensional framework, while compound 2 consists of cationic layers of [Bi2Se2Br](2+). Spectroscopically measured band gaps of 1 and 2 are similar to 0.6 and similar to 1.2 eV, respectively. Thermoelectric power measurements of single crystals of 1 indicate an n-type semiconductor.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.titleSemiconducting [(Bi4Te4Br2)(Al2Cl6-xBrx)]Cl-2 and [Bi2Se2Br](AlCl4): Cationic Chalcogenide Frameworks from Lewis Acidic Ionic Liquids-
dc.typeArticle-
dc.identifier.wosid000319720400012-
dc.identifier.scopusid2-s2.0-84877982948-
dc.type.rimsART-
dc.citation.volume52-
dc.citation.issue10-
dc.citation.beginningpage5657-
dc.citation.endingpage5659-
dc.citation.publicationnameINORGANIC CHEMISTRY-
dc.identifier.doi10.1021/ic400782c-
dc.contributor.localauthorChung, In-
dc.contributor.nonIdAuthorBiswas, Kanishka-
dc.contributor.nonIdAuthorSong, Jung-Hwan-
dc.contributor.nonIdAuthorMalliakas, Christos D.-
dc.contributor.nonIdAuthorFreeman, Arthur J.-
dc.contributor.nonIdAuthorKanatzidis, Mercouri G.-
dc.type.journalArticleArticle-
dc.subject.keywordPlusIONOTHERMAL SYNTHESIS-
dc.subject.keywordPlusMETAL NANOPARTICLES-
dc.subject.keywordPlusCHEMISTRY-
dc.subject.keywordPlusNANORODS-
dc.subject.keywordPlusSALTS-
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