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College of Natural Sciences(자연과학대학)Graduate School of Nanoscience and Technology(나노과학기술대학원)NT-Journal Papers(저널논문)

[P3Se7](3-): A Phosphorus-Rich Square-Ring Selenophosphate

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dc.contributor.authorChung, Inko
dc.contributor.authorHolmes, Danielko
dc.contributor.authorWeliky, David P.ko
dc.contributor.authorKanatzidis, Mercouri G.ko
dc.date.accessioned2013-03-12T10:09:58Z-
dc.date.available2013-03-12T10:09:58Z-
dc.date.created2013-01-28-
dc.date.created2013-01-28-
dc.date.issued2010-04-
dc.identifier.citationINORGANIC CHEMISTRY, v.49, no.7, pp.3092 - 3094-
dc.identifier.issn0020-1669-
dc.identifier.urihttp://hdl.handle.net/10203/101989-
dc.description.abstractThe new compound Cs10P8Se20 features the heterotetracyclic [P3Se7](3-) anion, a phosphorus-rich four-membered-ring species that possesses a P-P-P unit and formally P3+ and P4+ centers. It crystallizes in the orthorhombic space group Pnnm with a = 26.5456(7) angstrom, b = 8.0254(2) angstrom, c = 11.9031(4) angstrom, and Z = 2 at 100(2) K. The cyclic anion is cocrystallized with a [P2Se6](4-) anion. Electronic absorption, Raman, Fourier transform infrared, and solid-state P-31 NMR spectroscopy studies of Cs10P8Se20 are reported.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectMETAL POLYSELENOPHOSPHATE FLUXES-
dc.subjectPHASE-CHANGE PROPERTIES-
dc.subjectSOLID-STATE-
dc.subject2ND-HARMONIC GENERATION-
dc.subjectINTERMEDIATE TEMPERATURES-
dc.subjectCRYSTAL-STRUCTURES-
dc.subjectRB-
dc.subjectANION-
dc.subjectSALT-
dc.subjectNMR-
dc.title[P3Se7](3-): A Phosphorus-Rich Square-Ring Selenophosphate-
dc.typeArticle-
dc.identifier.wosid000276073000008-
dc.identifier.scopusid2-s2.0-77950279556-
dc.type.rimsART-
dc.citation.volume49-
dc.citation.issue7-
dc.citation.beginningpage3092-
dc.citation.endingpage3094-
dc.citation.publicationnameINORGANIC CHEMISTRY-
dc.identifier.doi10.1021/ic902561h-
dc.contributor.localauthorChung, In-
dc.contributor.nonIdAuthorHolmes, Daniel-
dc.contributor.nonIdAuthorWeliky, David P.-
dc.contributor.nonIdAuthorKanatzidis, Mercouri G.-
dc.type.journalArticleArticle-
dc.subject.keywordPlusMETAL POLYSELENOPHOSPHATE FLUXES-
dc.subject.keywordPlusPHASE-CHANGE PROPERTIES-
dc.subject.keywordPlusSOLID-STATE-
dc.subject.keywordPlus2ND-HARMONIC GENERATION-
dc.subject.keywordPlusINTERMEDIATE TEMPERATURES-
dc.subject.keywordPlusCRYSTAL-STRUCTURES-
dc.subject.keywordPlusRB-
dc.subject.keywordPlusANION-
dc.subject.keywordPlusSALT-
dc.subject.keywordPlusNMR-
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