Molecular resonances observed in the predissociation of Cs-2

Very cold molecular beam of Cs-2 is generated by a high temperature supersonic jet source. State-specific photofragment yield spectrum is obtained in the orange band of Cs-2. Asymmetric line shapes are observed. The Fano line shape parameter, q, shows a gradual sign change, which is called ''q-reversal''. A very broad absorption band which has about 50 cm(-1) width is observed and explained to occur through the perturbation by the D (1) Sigma(u)(+) state. The complex resonance line shapes are attributed to the interfering resonances.
Publisher
HARWOOD ACAD PUBL GMBH
Issue Date
1995
Language
ENG
Keywords

RESOLUTION LASER SPECTROSCOPY; IONIZATION SPECTROSCOPY; CS2; COMPLEX; STATE; BEAM; TRANSITION; SPECTRUM

Citation

LASER CHEMISTRY, v.16, no.1, pp.19 - 29

ISSN
0278-6273
DOI
10.1155/1995/79063
URI
http://hdl.handle.net/10203/10036
Appears in Collection
CH-Journal Papers(저널논문)
Files in This Item
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