DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, Jeong-Woo | ko |
dc.contributor.author | Ko, Jang-Myoun | ko |
dc.contributor.author | Kim, Jong-Duk | ko |
dc.date.accessioned | 2013-03-11T11:03:18Z | - |
dc.date.available | 2013-03-11T11:03:18Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2011-10 | - |
dc.identifier.citation | JOURNAL OF PHYSICAL CHEMISTRY C, v.115, no.39, pp.19445 - 19454 | - |
dc.identifier.issn | 1932-7447 | - |
dc.identifier.uri | http://hdl.handle.net/10203/99093 | - |
dc.description.abstract | Hierarchical microspheres composed of wrinkled alpha-Ni(OH)(2) nanosheets were synthesized from an aqueous solution containing nickel salts, hexamethylenetetramine, 1-butanol, and dodecyl sulfate. The exchange of intercalated dodecyl sulfate anions within the microspheres by smaller anions (Cl-, NO3-, OAc-, and SO42-) resulted in retention of morphology. A possible growth mechanism is proposed based on the observation of the effects the parameter variation (different nickel and hydroxide sources, several alcohols, with and without dodecyl sulfate as well as 1-butanol) had on rnicrosphere formation. Electrochemical and capacitive properties of the anion-exchanged microspheres were studied by cyclic voltammetry and galvanostatic charging-discharging. Interestingly, the specific capacitance was determined by size of the intercalated anions and not by the basal spacing; for example, the largest anion, SO42-, gave the lowest specific capacitance, whereas the smallest anion, Cl-, gave the highest specific capacitance. Our data support the notion that larger anions impede the mobility of OH- ions toward the surface of Ni(OH)(2) sheets to a greater extent than smaller ions. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | LAYERED DOUBLE HYDROXIDES | - |
dc.subject | ALPHA-NICKEL HYDROXIDE | - |
dc.subject | HYDROTHERMAL SYNTHESIS | - |
dc.subject | COBALT HYDROXIDES | - |
dc.subject | ZINC | - |
dc.subject | NANOSTRUCTURES | - |
dc.subject | SURFACTANT | - |
dc.subject | BEHAVIOR | - |
dc.subject | NANOCOMPOSITES | - |
dc.subject | DELAMINATION | - |
dc.title | Hierarchical Microspheres Based on alpha-Ni(OH)2 Nanosheets Intercalated with Different Anions: Synthesis, Anion Exchange, and Effect of Intercalated Anions on Electrochemical Capacitance | - |
dc.type | Article | - |
dc.identifier.wosid | 000295245500068 | - |
dc.identifier.scopusid | 2-s2.0-80053492665 | - |
dc.type.rims | ART | - |
dc.citation.volume | 115 | - |
dc.citation.issue | 39 | - |
dc.citation.beginningpage | 19445 | - |
dc.citation.endingpage | 19454 | - |
dc.citation.publicationname | JOURNAL OF PHYSICAL CHEMISTRY C | - |
dc.contributor.localauthor | Kim, Jong-Duk | - |
dc.contributor.nonIdAuthor | Ko, Jang-Myoun | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | LAYERED DOUBLE HYDROXIDES | - |
dc.subject.keywordPlus | ALPHA-NICKEL HYDROXIDE | - |
dc.subject.keywordPlus | HYDROTHERMAL SYNTHESIS | - |
dc.subject.keywordPlus | COBALT HYDROXIDES | - |
dc.subject.keywordPlus | ZINC | - |
dc.subject.keywordPlus | NANOSTRUCTURES | - |
dc.subject.keywordPlus | SURFACTANT | - |
dc.subject.keywordPlus | BEHAVIOR | - |
dc.subject.keywordPlus | NANOCOMPOSITES | - |
dc.subject.keywordPlus | DELAMINATION | - |
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