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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Highly Efficient and Versatile Synthesis of Polyarylfluorenes via Pd-Catalyzed C-H Bond Activation

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dc.contributor.authorHwang, Seung-Junko
dc.contributor.authorKim, Hyun-Jinko
dc.contributor.authorChang, Suk-Bokko
dc.date.accessioned2013-03-11T08:45:02Z-
dc.date.available2013-03-11T08:45:02Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2009-10-
dc.identifier.citationORGANIC LETTERS, v.11, no.20, pp.4588 - 4591-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10203/98838-
dc.description.abstractA facile protocol for the Pd-catalyzed preparative synthesis of fluorene derivatives has been developed. While a wide range of fluorenes; were easily obtained with high efficiency and selectivity under mild conditions, excellent functional group tolerance was also demonstrated. On the basis of Hammett and KIE studies, the present reaction is proposed to proceed via a base-assisted deprotonative metalation pathway.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectPROTON-ABSTRACTION MECHANISM-
dc.subjectDIRECT ARYLATION-
dc.subjectINTRAMOLECULAR ARYLATION-
dc.subjectHETEROAROMATIC-COMPOUNDS-
dc.subjectORGANIC ELECTRONICS-
dc.subjectFUNCTIONALIZATION-
dc.subjectDERIVATIVES-
dc.subjectFLUORENE-
dc.subjectARENES-
dc.titleHighly Efficient and Versatile Synthesis of Polyarylfluorenes via Pd-Catalyzed C-H Bond Activation-
dc.typeArticle-
dc.identifier.wosid000270461300027-
dc.identifier.scopusid2-s2.0-70349932317-
dc.type.rimsART-
dc.citation.volume11-
dc.citation.issue20-
dc.citation.beginningpage4588-
dc.citation.endingpage4591-
dc.citation.publicationnameORGANIC LETTERS-
dc.identifier.doi10.1021/ol901854f-
dc.embargo.liftdate9999-12-31-
dc.embargo.terms9999-12-31-
dc.contributor.localauthorChang, Suk-Bok-
dc.type.journalArticleArticle-
dc.subject.keywordPlusPROTON-ABSTRACTION MECHANISM-
dc.subject.keywordPlusDIRECT ARYLATION-
dc.subject.keywordPlusINTRAMOLECULAR ARYLATION-
dc.subject.keywordPlusHETEROAROMATIC-COMPOUNDS-
dc.subject.keywordPlusORGANIC ELECTRONICS-
dc.subject.keywordPlusFUNCTIONALIZATION-
dc.subject.keywordPlusDERIVATIVES-
dc.subject.keywordPlusFLUORENE-
dc.subject.keywordPlusARENES-
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