Anhydrous Hydration of Nitriles to Amides using Aldoximes as the Water Source

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Anhydrous hydrolysis of nitriles to amides was developed using acetaldoxime as the water source in the presence of Rh catalyst. Conversion of various nitriles to amides was performed under neutral and anhydrous conditions, and the reaction displays excellent compatibility with acid or base labile and hydrolytically labile functional groups.
Publisher
AMER CHEMICAL SOC
Issue Date
2009-12
Language
English
Article Type
Article
Citation

ORGANIC LETTERS, v.11, no.24, pp.5598 - 5601

ISSN
1523-7060
DOI
10.1021/ol902309z
URI
http://hdl.handle.net/10203/98495
Appears in Collection
CH-Journal Papers(저널논문)
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