DC Field | Value | Language |
---|---|---|
dc.contributor.author | Gal, Yeong-Soon | ko |
dc.contributor.author | Jin, Sung-Ho | ko |
dc.contributor.author | Park, Young-Il | ko |
dc.contributor.author | Park, Jong-Wook | ko |
dc.contributor.author | Lyoo, Won Seok | ko |
dc.contributor.author | Lim, Kwon Taek | ko |
dc.contributor.author | Kim, Sang Youl | ko |
dc.date.accessioned | 2013-03-11T04:40:28Z | - |
dc.date.available | 2013-03-11T04:40:28Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2011-06 | - |
dc.identifier.citation | FIBERS AND POLYMERS, v.12, no.3, pp.291 - 295 | - |
dc.identifier.issn | 1229-9197 | - |
dc.identifier.uri | http://hdl.handle.net/10203/98272 | - |
dc.description.abstract | Poly(1-hexyne) was prepared by the polymerization of 1-hexyne by using transition metal catalyst. The instrumental analysis data on the polymer structure revealed that the poly(1-hexyne) have the conjugated polyene backbone structure with n-butyl substituents. Poly(1-hexyne) showed UV-visible absorption band at 276 nm and PL spectrum at 415 nm, indicating relatively blue-shifted PL maximum value. From the relationship plot of the oxidation current density (log i(p),(a)) as a function of the scan rate (log v), it was found that the oxidation current of poly(1-hexyne) versus the scan rate is approximately linear relationship in the range of 30 similar to 150 mV/sec and the exponent of scan rate, x value is found to be 0.424. It is explained by that the kinetics of the redox process are close to the diffusion-control process. The band gap energy of poly(1-hexyne) was estimated to be 2.98 eV and HOMO and LUMO level values of poly(1-hexyne) were 5.35 and 2.37 eV, respectively. | - |
dc.language | English | - |
dc.publisher | KOREAN FIBER SOC | - |
dc.subject | LIGHT-EMITTING-DIODES | - |
dc.subject | TRANSITION-METAL CATALYSTS | - |
dc.subject | METATHESIS POLYMERIZATION | - |
dc.subject | ELECTRICAL-CONDUCTIVITY | - |
dc.subject | CONJUGATED POLYMERS | - |
dc.subject | POLYACETYLENE | - |
dc.subject | EFFICIENCY | - |
dc.subject | CYCLOPOLYMERIZATION | - |
dc.title | Electro-optical and Electrochemical Properties of Poly(1-hexyne) | - |
dc.type | Article | - |
dc.identifier.wosid | 000290739500001 | - |
dc.identifier.scopusid | 2-s2.0-79958054927 | - |
dc.type.rims | ART | - |
dc.citation.volume | 12 | - |
dc.citation.issue | 3 | - |
dc.citation.beginningpage | 291 | - |
dc.citation.endingpage | 295 | - |
dc.citation.publicationname | FIBERS AND POLYMERS | - |
dc.identifier.doi | 10.1007/s12221-011-0291-1 | - |
dc.contributor.localauthor | Kim, Sang Youl | - |
dc.contributor.nonIdAuthor | Gal, Yeong-Soon | - |
dc.contributor.nonIdAuthor | Jin, Sung-Ho | - |
dc.contributor.nonIdAuthor | Park, Young-Il | - |
dc.contributor.nonIdAuthor | Park, Jong-Wook | - |
dc.contributor.nonIdAuthor | Lyoo, Won Seok | - |
dc.contributor.nonIdAuthor | Lim, Kwon Taek | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | Poly(1-hexyne) | - |
dc.subject.keywordAuthor | Conjugated polymer | - |
dc.subject.keywordAuthor | Characterization | - |
dc.subject.keywordAuthor | Cyclovoltamogram | - |
dc.subject.keywordAuthor | Photoluminescence | - |
dc.subject.keywordPlus | LIGHT-EMITTING-DIODES | - |
dc.subject.keywordPlus | TRANSITION-METAL CATALYSTS | - |
dc.subject.keywordPlus | METATHESIS POLYMERIZATION | - |
dc.subject.keywordPlus | ELECTRICAL-CONDUCTIVITY | - |
dc.subject.keywordPlus | CONJUGATED POLYMERS | - |
dc.subject.keywordPlus | POLYACETYLENE | - |
dc.subject.keywordPlus | EFFICIENCY | - |
dc.subject.keywordPlus | CYCLOPOLYMERIZATION | - |
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