DC Field | Value | Language |
---|---|---|
dc.contributor.author | Egorova, Olga A. | ko |
dc.contributor.author | Tsay, Olga G. | ko |
dc.contributor.author | Khatua, Snehadrinarayan | ko |
dc.contributor.author | Meka, Bhupal | ko |
dc.contributor.author | Maiti, Nilkamal | ko |
dc.contributor.author | Kim, Min-Kyu | ko |
dc.contributor.author | Kwon, Seong-Jung | ko |
dc.contributor.author | Huh, Jung-Oh | ko |
dc.contributor.author | Bucella, Daniela | ko |
dc.contributor.author | Kang, Sa-Ouk | ko |
dc.contributor.author | Kwak, Ju-Hyoun | ko |
dc.contributor.author | Churchill, David G | ko |
dc.date.accessioned | 2013-03-11T03:56:53Z | - |
dc.date.available | 2013-03-11T03:56:53Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2010-01 | - |
dc.identifier.citation | INORGANIC CHEMISTRY, v.49, no.2, pp.502 - 512 | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.uri | http://hdl.handle.net/10203/98197 | - |
dc.description.abstract | We report eight new A(2)B-type (Mn+) corrolate compounds (two structural studies) that include the oxo[5,15bis(pentafluorophenyl)-10-R-corrolatochromium(V)] [R = 2-/3-thienyl (1a/2a), 3-thianaphthyl (3a)] species. The first examples of meso-A(2) (thienyl)- and Cr-A(2)B-corrole types are represented herein. Characterization includes cyclic voltammetry, electron paramagnetic resonance, 2D (H-1 and C-13) NMR, and UV-vis spectroscopy, mass spectrometry, and elemental analysis. Compounds 1a-3a have enabled analyte binding capacity studies. [Cu2+center dot center dot center dot O=Cr(cor)] binding represents a new selective mode of corrole-based detection, whereas free-base A(2)B-corroles exhibited limited Mn+ selectivity. The 10-position substitution affects optical profiles in analyte titrations. A limited amount of PPh3 O-atom uptake from [O=Cr(cor)] was also demonstrated. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | LIQUID-MEMBRANE ELECTRODES | - |
dc.subject | ARYL SUBSTITUTED CORROLES | - |
dc.subject | CHROMIUM CORROLES | - |
dc.subject | COBALT(III) CORROLES | - |
dc.subject | FREE-BASE | - |
dc.subject | COMPLEXES | - |
dc.subject | OXIDATION | - |
dc.subject | 5,10,15-TRIS(PENTAFLUOROPHENYL)CORROLE | - |
dc.subject | MACROCYCLES | - |
dc.subject | DERIVATIVES | - |
dc.title | Synthetic, Cyclic Voltammetric, Structural, EPR, and UV-Vis Spectroscopic Studies of Thienyl-Containing meso-A(2)B-cor(Cr(v)=0) Systems: Consideration of Three Interrelated Molecular Detection Modalities | - |
dc.type | Article | - |
dc.identifier.wosid | 000273402900023 | - |
dc.identifier.scopusid | 2-s2.0-74549137298 | - |
dc.type.rims | ART | - |
dc.citation.volume | 49 | - |
dc.citation.issue | 2 | - |
dc.citation.beginningpage | 502 | - |
dc.citation.endingpage | 512 | - |
dc.citation.publicationname | INORGANIC CHEMISTRY | - |
dc.identifier.doi | 10.1021/ic9021432 | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Kwak, Ju-Hyoun | - |
dc.contributor.localauthor | Churchill, David G | - |
dc.contributor.nonIdAuthor | Egorova, Olga A. | - |
dc.contributor.nonIdAuthor | Khatua, Snehadrinarayan | - |
dc.contributor.nonIdAuthor | Meka, Bhupal | - |
dc.contributor.nonIdAuthor | Maiti, Nilkamal | - |
dc.contributor.nonIdAuthor | Kim, Min-Kyu | - |
dc.contributor.nonIdAuthor | Huh, Jung-Oh | - |
dc.contributor.nonIdAuthor | Bucella, Daniela | - |
dc.contributor.nonIdAuthor | Kang, Sa-Ouk | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | LIQUID-MEMBRANE ELECTRODES | - |
dc.subject.keywordPlus | ARYL SUBSTITUTED CORROLES | - |
dc.subject.keywordPlus | CHROMIUM CORROLES | - |
dc.subject.keywordPlus | COBALT(III) CORROLES | - |
dc.subject.keywordPlus | FREE-BASE | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | OXIDATION | - |
dc.subject.keywordPlus | 5,10,15-TRIS(PENTAFLUOROPHENYL)CORROLE | - |
dc.subject.keywordPlus | MACROCYCLES | - |
dc.subject.keywordPlus | DERIVATIVES | - |
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