DC Field | Value | Language |
---|---|---|
dc.contributor.author | Reiff, William M. | ko |
dc.contributor.author | Schulz, Charles E. | ko |
dc.contributor.author | Whangbo, Myung-Hwan | ko |
dc.contributor.author | Seo, Jung In | ko |
dc.contributor.author | Lee, Yoon Sup | ko |
dc.contributor.author | Potratz, Gregory R. | ko |
dc.contributor.author | Spicer, Charles W. | ko |
dc.contributor.author | Girolami, Gregory S. | ko |
dc.date.accessioned | 2013-03-11T03:56:04Z | - |
dc.date.available | 2013-03-11T03:56:04Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2009-01 | - |
dc.identifier.citation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.131, no.2, pp.404 - 404 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | http://hdl.handle.net/10203/98196 | - |
dc.description.abstract | Mossbauer, EPR, magnetic susceptibility, and DFT studies of the unusual two-coordinate iron(II) amide Fe[N(t-Bu)(2)](2) show that it retains a linear N-Fe-N framework due to the nonbonding delta nature of the (xy, x(2)-y(2)) orbitals. The resulting near-degenerate ground state gives rise to a large magnetic moment and a remarkably large internal hyperfine field. The results confirm that extraordinary orbital magnetic effects can arise in linear transition metal complexes in which orbital degeneracies are not broken by Jahn-Teller or Renner-Teller distortions. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | FREE-ION | - |
dc.subject | TRANSITION | - |
dc.subject | FE | - |
dc.subject | CRYSTALLINE | - |
dc.subject | DERIVATIVES | - |
dc.subject | AMIDES | - |
dc.subject | CR | - |
dc.subject | MN | - |
dc.subject | NI | - |
dc.subject | CO | - |
dc.title | Consequences of a Linear Two-Coordinate Geometry for the Orbital Magnetism and Jahn-Teller Distortion Behavior of the High Spin Iron(II) Complex Fe[N(t-Bu)(2)](2) | - |
dc.type | Article | - |
dc.identifier.wosid | 000262521800004 | - |
dc.identifier.scopusid | 2-s2.0-67749114506 | - |
dc.type.rims | ART | - |
dc.citation.volume | 131 | - |
dc.citation.issue | 2 | - |
dc.citation.beginningpage | 404 | - |
dc.citation.endingpage | 404 | - |
dc.citation.publicationname | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.identifier.doi | 10.1021/ja806660f | - |
dc.contributor.localauthor | Lee, Yoon Sup | - |
dc.contributor.nonIdAuthor | Reiff, William M. | - |
dc.contributor.nonIdAuthor | Schulz, Charles E. | - |
dc.contributor.nonIdAuthor | Whangbo, Myung-Hwan | - |
dc.contributor.nonIdAuthor | Potratz, Gregory R. | - |
dc.contributor.nonIdAuthor | Spicer, Charles W. | - |
dc.contributor.nonIdAuthor | Girolami, Gregory S. | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | FREE-ION | - |
dc.subject.keywordPlus | TRANSITION | - |
dc.subject.keywordPlus | FE | - |
dc.subject.keywordPlus | CRYSTALLINE | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | AMIDES | - |
dc.subject.keywordPlus | CR | - |
dc.subject.keywordPlus | MN | - |
dc.subject.keywordPlus | NI | - |
dc.subject.keywordPlus | CO | - |
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