DC Field | Value | Language |
---|---|---|
dc.contributor.author | Moon, Jung-Hee | ko |
dc.contributor.author | Kim, So-Han | ko |
dc.contributor.author | Lee, Kang-Mun | ko |
dc.contributor.author | You, Tae-Soo | ko |
dc.contributor.author | Do, Young-Kyu | ko |
dc.contributor.author | Kim, Young-Jo | ko |
dc.date.accessioned | 2013-03-11T01:38:04Z | - |
dc.date.available | 2013-03-11T01:38:04Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2011-08 | - |
dc.identifier.citation | POLYHEDRON, v.30, no.13, pp.2333 - 2338 | - |
dc.identifier.issn | 0277-5387 | - |
dc.identifier.uri | http://hdl.handle.net/10203/97941 | - |
dc.description.abstract | Three monomeric germatranes, 1-isopropoxy-3,3,7,7,10,10-hexamethyl-2,8,9-trioxa-5-aza-1-germatricyclo[3.3.3.0(1.5)]undecane (1), 1-isopropoxy-3,3,7,7-tetramethyl-2,8,9-trioxa-5-aza-1-germatricyclo[3.33.0(1.5)]undecane (2), and 1-isopropoxy-3,3-dimethyl-2,8,9-trioxa-5-aza-1-germatricyclo[3.3.3.0(1.5)]undecane (3) have been synthesized by the reaction of Ge(O-i-Pr)(4) in refluxing toluene with corresponding triethanolamines, (HOCH(2)CH(2))(n)N(CH(2)CMe(2)OH)(3-n) (n = 0, L1H(3); n = 1, L2H(3); n = 2, L3H(3)), where the number of CMe(2) groups adjacent to a OH functionality varied from 3 (L1H(3)) to 2 (L2H(3)), and to 1 (L3H(3)). These germatranes 1-3 have been characterized by solution (1)H and (13)C{(1)H) NMR and the solid state structure of 2 has been determined by single crystal X-ray diffraction. (C) 2011 Elsevier Ltd. All rights reserved. | - |
dc.language | English | - |
dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | - |
dc.subject | MOLECULAR-STRUCTURE | - |
dc.subject | CRYSTAL-STRUCTURE | - |
dc.subject | ORGANOGERMANIUM COMPOUNDS | - |
dc.subject | MOIETIES | - |
dc.subject | SKELETON | - |
dc.subject | ATRANES | - |
dc.subject | PHENYL | - |
dc.title | Synthesis and X-ray diffraction analysis/crystal structure of new germatranes containing methyl substituents in three five-membered chelating rings | - |
dc.type | Article | - |
dc.identifier.wosid | 000294572900021 | - |
dc.identifier.scopusid | 2-s2.0-79960979913 | - |
dc.type.rims | ART | - |
dc.citation.volume | 30 | - |
dc.citation.issue | 13 | - |
dc.citation.beginningpage | 2333 | - |
dc.citation.endingpage | 2338 | - |
dc.citation.publicationname | POLYHEDRON | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Do, Young-Kyu | - |
dc.contributor.nonIdAuthor | Moon, Jung-Hee | - |
dc.contributor.nonIdAuthor | Kim, So-Han | - |
dc.contributor.nonIdAuthor | You, Tae-Soo | - |
dc.contributor.nonIdAuthor | Kim, Young-Jo | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | Germatrane | - |
dc.subject.keywordAuthor | 1-Isopropoxy-2,8,9-trioxa-5-aza-1-germatricyclo[3.3.3.0(1.5)]undecane | - |
dc.subject.keywordAuthor | 1-Isopropoxy-3,3-dimethyl-2,8,9-trioxa-5-aza-1-germatricyclo[3.3.3.0(1.5)]undecane | - |
dc.subject.keywordAuthor | 1-Isopropoxy-3,3,7,7-tetramethyl-2,8,9-trioxa-5-aza-1-germatricyclo[3.3.3.0(1.5)]undecane 1-Isopropoxy-3,3,7.7,10.10-hexamethyl-2,8,9-trioxa-5-aza-1-germatricyclo[3.3.3.0(1.5)]undecane | - |
dc.subject.keywordAuthor | Transannular interaction | - |
dc.subject.keywordAuthor | X-ray crystal structure | - |
dc.subject.keywordPlus | MOLECULAR-STRUCTURE | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURE | - |
dc.subject.keywordPlus | ORGANOGERMANIUM COMPOUNDS | - |
dc.subject.keywordPlus | MOIETIES | - |
dc.subject.keywordPlus | SKELETON | - |
dc.subject.keywordPlus | ATRANES | - |
dc.subject.keywordPlus | PHENYL | - |
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