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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Thioether S-ligation in a side-on mu-eta(2):eta(2)-peroxodicopper(II) complex

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dc.contributor.authorPark, GYko
dc.contributor.authorLee, Yunhoko
dc.contributor.authorLee, DHko
dc.contributor.authorWoertink, JSko
dc.contributor.authorSarjeant, AANko
dc.contributor.authorSolomon, EIko
dc.contributor.authorKarlin, KDko
dc.date.accessioned2013-03-11T00:01:23Z-
dc.date.available2013-03-11T00:01:23Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2010-01-
dc.identifier.citationCHEMICAL COMMUNICATIONS, v.46, no.1, pp.91 - 93-
dc.identifier.issn1359-7345-
dc.identifier.urihttp://hdl.handle.net/10203/97739-
dc.description.abstract[(ANS)Cu-I(CH3CN)](+) reacts with O-2 giving [{(ANS)Cu-II}(2)(mu-eta(2):eta(2)-O-2(2-))](2+), nu(O-O) = 731 cm(-1), shown to possess S-thioether ligation, based on comparisons with analogues having all N-ligands or a -S(Ph) group. The finding is a rare occurrence and new for side-on O-2(2-) binding.-
dc.languageEnglish-
dc.publisherROYAL SOC CHEMISTRY-
dc.subjectALPHA-HYDROXYLATING MONOOXYGENASE-
dc.subjectINCLUDING SULFUR-LIGATION-
dc.subjectCOPPER-DIOXYGEN CHEMISTRY-
dc.subjectCATALYTIC MECHANISM-
dc.subjectMONONUCLEAR COPPER-
dc.subjectBETA-MONOOXYGENASE-
dc.subjectEND-ON-
dc.subjectREACTIVITY-
dc.subjectLIGAND-
dc.subjectDOPAMINE-
dc.titleThioether S-ligation in a side-on mu-eta(2):eta(2)-peroxodicopper(II) complex-
dc.typeArticle-
dc.identifier.wosid000272679200014-
dc.identifier.scopusid2-s2.0-72149113628-
dc.type.rimsART-
dc.citation.volume46-
dc.citation.issue1-
dc.citation.beginningpage91-
dc.citation.endingpage93-
dc.citation.publicationnameCHEMICAL COMMUNICATIONS-
dc.identifier.doi10.1039/b918616f-
dc.contributor.localauthorLee, Yunho-
dc.contributor.nonIdAuthorPark, GY-
dc.contributor.nonIdAuthorLee, DH-
dc.contributor.nonIdAuthorWoertink, JS-
dc.contributor.nonIdAuthorSarjeant, AAN-
dc.contributor.nonIdAuthorSolomon, EI-
dc.contributor.nonIdAuthorKarlin, KD-
dc.type.journalArticleArticle-
dc.subject.keywordPlusALPHA-HYDROXYLATING MONOOXYGENASE-
dc.subject.keywordPlusINCLUDING SULFUR-LIGATION-
dc.subject.keywordPlusCOPPER-DIOXYGEN CHEMISTRY-
dc.subject.keywordPlusCATALYTIC MECHANISM-
dc.subject.keywordPlusMONONUCLEAR COPPER-
dc.subject.keywordPlusBETA-MONOOXYGENASE-
dc.subject.keywordPlusEND-ON-
dc.subject.keywordPlusREACTIVITY-
dc.subject.keywordPlusLIGAND-
dc.subject.keywordPlusDOPAMINE-
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