Electronic Structure and Bonding Configuration of Histidine on Ge(100)

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The electronic structures and bonding configuration of histidine on Ge(100) have been investigated with various sample treatments using core-level photoemission spectroscopy (CLPES) Interpretation of the Ge 3d, C 1s, N 1s, and O 1s core level spectra being included in these systems revealed that both the imino nitrogen in the imidazole ring and the carboxyl group in the glycine moiety concurrently participate in the adsorption of histidine on a Ge(100) surface at 380 K Moreover, we could clearly confirm that the imino nitrogen with a free lone pair in the imidazole group adsorbs on Ge(100) more strongly than the carboxyl group in the glycine moiety by examining systems annealed at various temperatures
Publisher
KOREAN CHEMICAL SOC
Issue Date
2010-11
Language
English
Article Type
Article
Keywords

SEMICONDUCTOR SURFACES; BINDING-SPECIFICITY; ADSORPTION; CHEMISTRY; GLYCINE; CYCLOADDITION

Citation

BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.31, no.11, pp.3217 - 3220

ISSN
0253-2964
DOI
10.5012/bkcs.2010.31.11.3217
URI
http://hdl.handle.net/10203/97715
Appears in Collection
CH-Journal Papers(저널논문)
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