DC Field | Value | Language |
---|---|---|
dc.contributor.author | Muroyama, Norihiro | ko |
dc.contributor.author | Yoshimura, Arisa | ko |
dc.contributor.author | Kubota, Yoshiki | ko |
dc.contributor.author | Miyasaka, Keiichi | ko |
dc.contributor.author | Ohsuna, Tetsu | ko |
dc.contributor.author | Ryoo, Ryong | ko |
dc.contributor.author | Ravikovitch, Peter I. | ko |
dc.contributor.author | Neimark, Alexander V. | ko |
dc.contributor.author | Takata, Masaki) | ko |
dc.contributor.author | Terasaki, Osamu | ko |
dc.date.accessioned | 2009-06-25T02:35:04Z | - |
dc.date.available | 2009-06-25T02:35:04Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2008-07 | - |
dc.identifier.citation | JOURNAL OF PHYSICAL CHEMISTRY C, v.112, no.29, pp.10803 - 10813 | - |
dc.identifier.issn | 1932-7447 | - |
dc.identifier.uri | http://hdl.handle.net/10203/9737 | - |
dc.description.abstract | Equilibrium argon adsorption from the gas phase on mesoporous MCM-41 silica of hexagonal structure is directly studied by in situ synchrotron powder X-ray diffraction (XRD) measurements at SPring-8. The diffraction intensity data is analyzed by extending the previously developed analytical formula for the crystal structure factors of MCM-41 to account for argon adsorbed in the pores. It is clearly observed that argon adsorbs in layers on the pore walls at low gas pressures and exhibits sudden capillary condensation as the gas pressure increased. The proposed method of interpretation of XRD data allows one to calculate the density ratio between the silica wall and condensed argon, the pore size, and the pore wall fluctuation/roughness, together with the thickness of the adsorbed layer as a function of the gas pressure. The results of in situ XRD experiments are compared with the results of argon adsorption volumetric experiments.' The adsorption data are interpreted with the quench solid density functional theory (QSDFT), which takes into account the pore wall roughness. The perfect agreement of the QSDFT isotherm predicted from the adsorption data and the XRD recalculated isotherm suggests that the adsorption porosimetry and XRD measurements can be reconciled provided a proper interpretation of the experimental data. | - |
dc.description.sponsorship | Financial support from the Swedish Research Council (VR) and Japanese Science and Technology Agency (JST) are acknowledged. This study was partly supported by a Grant-In-Aid for Science Research from the Ministry of Education, Culture, Sports, Science and Technology of Japan. This study was also supported by JASRI/SPring-8 Nanotechnology Support Project of the Ministry of Education, Culture, Sports, Science and Technology of Japan. The authors thank Drs. K. Kato and K. Osaka of JASRI for their kind advice and help in data collection. R.R. acknowledges support from the Ministry of Education, Science, and Technology through the National Honor Scientist Program. A.N.V. acknowledges a grant from Quantachrome Instruments and thanks Dr. M. Thommes for fruitful discussions. | en |
dc.language | English | - |
dc.language.iso | en_US | en |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | NITROGEN ADSORPTION | - |
dc.subject | PORE-SIZE | - |
dc.subject | ELECTRON CRYSTALLOGRAPHY | - |
dc.subject | CAPILLARY CONDENSATION | - |
dc.subject | WALL STRUCTURE | - |
dc.subject | SILICA | - |
dc.subject | SCATTERING | - |
dc.title | Argon adsorption on MCM-41 mesoporous crystal studied by in situ synchrotron powder X-ray diffraction | - |
dc.type | Article | - |
dc.identifier.wosid | 000257724100035 | - |
dc.identifier.scopusid | 2-s2.0-49149130549 | - |
dc.type.rims | ART | - |
dc.citation.volume | 112 | - |
dc.citation.issue | 29 | - |
dc.citation.beginningpage | 10803 | - |
dc.citation.endingpage | 10813 | - |
dc.citation.publicationname | JOURNAL OF PHYSICAL CHEMISTRY C | - |
dc.identifier.doi | 10.1021/jp800385t | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Ryoo, Ryong | - |
dc.contributor.nonIdAuthor | Muroyama, Norihiro | - |
dc.contributor.nonIdAuthor | Yoshimura, Arisa | - |
dc.contributor.nonIdAuthor | Kubota, Yoshiki | - |
dc.contributor.nonIdAuthor | Miyasaka, Keiichi | - |
dc.contributor.nonIdAuthor | Ohsuna, Tetsu | - |
dc.contributor.nonIdAuthor | Ravikovitch, Peter I. | - |
dc.contributor.nonIdAuthor | Neimark, Alexander V. | - |
dc.contributor.nonIdAuthor | Takata, Masaki) | - |
dc.contributor.nonIdAuthor | Terasaki, Osamu | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | NITROGEN ADSORPTION | - |
dc.subject.keywordPlus | PORE-SIZE | - |
dc.subject.keywordPlus | ELECTRON CRYSTALLOGRAPHY | - |
dc.subject.keywordPlus | CAPILLARY CONDENSATION | - |
dc.subject.keywordPlus | WALL STRUCTURE | - |
dc.subject.keywordPlus | SILICA | - |
dc.subject.keywordPlus | SCATTERING | - |
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