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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Rhodium-Catalyzed Selective Olefination of Arene Esters via C-H Bond Activation

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dc.contributor.authorPark, Sae-Humeko
dc.contributor.authorKim, Ji-Youngko
dc.contributor.authorChang, Suk-Bokko
dc.date.accessioned2013-03-09T11:26:07Z-
dc.date.available2013-03-09T11:26:07Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2011-05-
dc.identifier.citationORGANIC LETTERS, v.13, no.9, pp.2372 - 2375-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10203/96226-
dc.description.abstractA new catalytic procedure of ortho-olefination of benzoates and benzaldehydes has been developed. Ester and carboxaldehyde units were revealed to be effective chelating groups in focusing the activation of aryl C-H bonds ortho to the directing moieties under the Rh-catalyzed oxidative conditions. The reaction is highly regioselective with a range of benzoates and benzaldehydes enabling the efficient olefination with acrylates, acrylic acid, and styrenes.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectBENZOIC-ACIDS-
dc.subjectAROMATIC KETONES-
dc.subjectINTERNAL ALKYNES-
dc.subjectCARBOXYLIC-ACIDS-
dc.subjectDIRECT AMINATION-
dc.subjectDIRECT ARYLATION-
dc.subjectARYL KETONES-
dc.subjectDERIVATIVES-
dc.subjectALKENES-
dc.subjectFUNCTIONALIZATION-
dc.titleRhodium-Catalyzed Selective Olefination of Arene Esters via C-H Bond Activation-
dc.typeArticle-
dc.identifier.wosid000289956700059-
dc.identifier.scopusid2-s2.0-79955613681-
dc.type.rimsART-
dc.citation.volume13-
dc.citation.issue9-
dc.citation.beginningpage2372-
dc.citation.endingpage2375-
dc.citation.publicationnameORGANIC LETTERS-
dc.contributor.localauthorChang, Suk-Bok-
dc.type.journalArticleArticle-
dc.subject.keywordPlusBENZOIC-ACIDS-
dc.subject.keywordPlusAROMATIC KETONES-
dc.subject.keywordPlusINTERNAL ALKYNES-
dc.subject.keywordPlusCARBOXYLIC-ACIDS-
dc.subject.keywordPlusDIRECT AMINATION-
dc.subject.keywordPlusDIRECT ARYLATION-
dc.subject.keywordPlusARYL KETONES-
dc.subject.keywordPlusDERIVATIVES-
dc.subject.keywordPlusALKENES-
dc.subject.keywordPlusFUNCTIONALIZATION-
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CH-Journal Papers(저널논문)
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