DC Field | Value | Language |
---|---|---|
dc.contributor.author | Morris, William | ko |
dc.contributor.author | Doonan, Christian J. | ko |
dc.contributor.author | Yaghi, Omar M. | ko |
dc.date.accessioned | 2013-03-09T10:13:52Z | - |
dc.date.available | 2013-03-09T10:13:52Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2011-08 | - |
dc.identifier.citation | INORGANIC CHEMISTRY, v.50, no.15, pp.6853 - 6855 | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.uri | http://hdl.handle.net/10203/96067 | - |
dc.description.abstract | In our study, we show by solid-state (15)N NMR measurements that an important zirconium metal-organic framework (UiO-66) with amino-functionalized links is composed of a mixture of amino and -NH(3)(+)Cl(-) salt functionalities rather than all amino functionality to give a composition of Zr(6)O(4)(OH)(4)(BDC-NH(2))(4)(BDC-NH(3)(+)Cl(-))(2) (UiO-66-A). UiO-66-A was postsynthetically modified to form a mixture of three functionalities, where the hemiaminal functionality is the majority species in UiO-66-B and aziridine is the majority functionality in UiO-66-C. UiO-66-A-C are all porous with surface areas ranging from 780 to 820 m(2)/g and have chemical stability, as evidenced by reversible ammonia uptake and release showing capacities ranging from 134 to 193 cm(3)/g. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | FUNCTIONALIZATION | - |
dc.subject | STABILITY | - |
dc.title | Postsynthetic Modification of a Metal-Organic Framework for Stabilization of a Hemiaminal and Ammonia Uptake | - |
dc.type | Article | - |
dc.identifier.wosid | 000293036000003 | - |
dc.identifier.scopusid | 2-s2.0-79960793591 | - |
dc.type.rims | ART | - |
dc.citation.volume | 50 | - |
dc.citation.issue | 15 | - |
dc.citation.beginningpage | 6853 | - |
dc.citation.endingpage | 6855 | - |
dc.citation.publicationname | INORGANIC CHEMISTRY | - |
dc.identifier.doi | 10.1021/ic200744y | - |
dc.contributor.nonIdAuthor | Morris, William | - |
dc.contributor.nonIdAuthor | Doonan, Christian J. | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | FUNCTIONALIZATION | - |
dc.subject.keywordPlus | STABILITY | - |
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