Practical beta-masked formylation and acetylation of electron-deficient olefins utilizing tetra(n-butyl)ammonium peroxydisulfate

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Various electron-deficient olefins reacted readily with 1,3-dioxolane or 2-methyl-1,3-dioxlane in the presence of TBAP to afford the corresponding 1,3-dioxolanylated or 2-methyl-1,3-dioxolanylated products in a complete regioselective manner in good to excellent yields. (C) 2011 Elsevier Ltd. All rights reserved.
Publisher
Pergamon-Elsevier Science Ltd
Issue Date
2011
Language
English
Article Type
Article
Keywords

N-BUTYLAMMONIUM PEROXYDISULFATE; CIS-JASMONE; CARBONYL-COMPOUNDS; DERIVATIVES; 1,4-DIKETONES; 1,3-DIOXOLANE; 1,5-DIKETONES; ALCOHOLS; ACETALS; ENONES

Citation

TETRAHEDRON LETTERS, v.52, no.36, pp.4662 - 4664

ISSN
0040-4039
URI
http://hdl.handle.net/10203/96053
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